Loading…
A fourth polymorph in the family of BEDT-TTF salts with thiocyanatocuprate(I) anions: (BEDT-TTF){<_4}Cu{<_3}(NCS){<_5}
A new crystallographic modification was found in the family of BEDT-TTF salts containing thiocyanatocuprate(I) anions. The cation radical salt crystallizes in the P{sup {bar 1}} space group with a = 8.2720(9) {angstrom}, b = 19.099(2) {angstrom}, c = 43.758(5) {angstrom}, {alpha} = 81.088(4){sup o},...
Saved in:
Published in: | Physica Status Solidi B (Basic Research) 2012-05, Vol.249 (5) |
---|---|
Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | A new crystallographic modification was found in the family of BEDT-TTF salts containing thiocyanatocuprate(I) anions. The cation radical salt crystallizes in the P{sup {bar 1}} space group with a = 8.2720(9) {angstrom}, b = 19.099(2) {angstrom}, c = 43.758(5) {angstrom}, {alpha} = 81.088(4){sup o}, {beta} = 87.253(4){sup o}, {gamma} = 83.790(4){sup o}, V = 6786.2(13) {angstrom}{sup 3} at 150 K. The BEDT-TTF radical cations pack in an {alpha}-type motif, but every four columns, there is a slip in the layer. Where this slip occurs, the stacks are coupled in a {beta}'' manner. The material exhibits semiconductive behavior with an activation energy of 0.13 eV above 250 K and 0.22 eV below. Packing motif of the (BEDT-TTF){sub 4}Cu{sub 3}(NCS){sub 5} structure. |
---|---|
ISSN: | 0370-1972 1521-3951 |
DOI: | 10.1002/pssb.201100726 |