Regio- and Stereocontrolled Nucleophilic Addition Reactions of a Phenylthio-Substituted Cyclohexadiene-Containing η4-Molybdenum Cationic Complex

The reaction of a new cationic complex, [Cp(CO)2Mo(η4-2-SPh-C6H7)]+PF6 - (3), with carbon and sulfur nucleophiles was found to give in most cases the C-4 addition products 4 in good yield. The X-ray crystal structure of one of the addition products 4b confirms the regio- and stereochemistry of the r...

Full description

Saved in:
Bibliographic Details
Published in:Organometallics 1996-10, Vol.15 (20), p.4113-4115
Main Authors: Chou, Shang-Shing P, Sheng, Hui-Tuo
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The reaction of a new cationic complex, [Cp(CO)2Mo(η4-2-SPh-C6H7)]+PF6 - (3), with carbon and sulfur nucleophiles was found to give in most cases the C-4 addition products 4 in good yield. The X-ray crystal structure of one of the addition products 4b confirms the regio- and stereochemistry of the reaction.
ISSN:0276-7333
1520-6041
DOI:10.1021/om960499z