A focus on applying 63/65 Cu solid-state NMR spectroscopy to characterize Cu MOFs

Metal-organic frameworks (MOFs) are a class of hybrid organic and inorganic porous materials that have shown prospects in applications ranging from gas storage, separation, catalysis, Although they can be studied using various characterization techniques, these methods often do not provide local str...

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Bibliographic Details
Published in:Chemical science (Cambridge) 2024-05, Vol.15 (18), p.6604-6607
Main Authors: Pang, Zhenfeng, Tan, Kong Ooi
Format: Article
Language:English
Subjects:
Chemical Sciences
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Summary:Metal-organic frameworks (MOFs) are a class of hybrid organic and inorganic porous materials that have shown prospects in applications ranging from gas storage, separation, catalysis, Although they can be studied using various characterization techniques, these methods often do not provide local structural details that help explain their functionality. Zhang (W. Zhang, B. E. G. Lucier, V. V. Terskikh, S. Chen and Y. Huang, , 2024, https://doi.org/10.1039/D4SC00782D) have recently exploited Cu solid-state NMR spectroscopy (for the first time) and DFT calculations to elucidate the structures of Cu(i) centers in MOFs. While there are still many challenges in overcoming issues in resolution and sensitivity, this work lays the foundation for further development of solid-state NMR technology in characterizing copper in MOFs or other amorphous solids.
ISSN:2041-6520
2041-6539
DOI:10.1039/D4SC90069C