Photocatalytic Activity of Ruthenium(II) Complex with 1,10-Phenanthroline-3,8-dicarboxylic Acid in Aerobic Oxidation Reactions

Mixed-ligand ruthenium(II) complex with 2,2′-bipyridine and 1,10-phenanthroline-3,8-dicarboxylic acid with the composition [Ru(phen-C)(bpy) 2 ]Cl 2 ·5H 2 O (bpy = 2,2′-bipyridine, phen-C = 1,10-phenantroline-3,8-dicarboxylic acid) has been synthesized and characterized by spectral data. The complex...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2021-09, Vol.57 (9), p.1398-1404
Main Authors: Zenkov, I. S., Yakushev, A. A., Abel, A. S., Averin, A. D., Bessmertnykh-Lemeune, A. G., Beletskaya, I. P.
Format: Article
Language:eng ; rus
Subjects:
Amines
Aqueous solutions
Catalytic activity
Chemical Sciences
Chemistry
Chemistry and Materials Science
Coordination compounds
Dicarboxylic acids
Imines
Organic Chemistry
Oxidation
Phenols
Photocatalysis
Regeneration
Ruthenium
Ruthenium compounds
Sulfides
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Summary:Mixed-ligand ruthenium(II) complex with 2,2′-bipyridine and 1,10-phenanthroline-3,8-dicarboxylic acid with the composition [Ru(phen-C)(bpy) 2 ]Cl 2 ·5H 2 O (bpy = 2,2′-bipyridine, phen-C = 1,10-phenantroline-3,8-dicarboxylic acid) has been synthesized and characterized by spectral data. The complex has been tested as photocatalyst in aerobic oxidation reactions, including transformation of arylboronic acids to phenols, primary amines to imines, and sulfides to sulfoxides in aqueous medium. The possibility of regeneration of the catalyst in the oxidation of sulfides has been demonstrated.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428021090025