SnO2 "Russian Doll" Octahedra Prepared by Metalorganic Synthesis: A New Structure for Sub-ppm CO Detection

Micrometer‐sized hierarchical Sn3O2(OH)2 octahedra, which are self‐assembled one inside the other, resembling “Russian doll” organization, have been obtained by a metalorganic approach. This synthesis is based on the controlled hydrolysis of [Sn(NMe2)2]2 in the presence of an alkylamine ligand in an...

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Bibliographic Details
Published in:Chemistry : a European journal 2016-07, Vol.22 (29), p.10127-10135
Main Authors: Jońca, Justyna, Ryzhikov, Andrey, Kahn, Myrtil L., Fajerwerg, Katia, Chapelle, Audrey, Menini, Philippe, Fau, Pierre
Format: Article
Language:English
Subjects:
Chemical Sciences
Chemistry
Coordination chemistry
hierarchical structures
Hydrolysis
metalorganic synthesis
Micromachining
Moisture content
nanoparticles
Operating temperature
sensors
Silicon
Silicon devices
SnO2
Synthesis
Temperature effects
Tin dioxide
Water content
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Summary:Micrometer‐sized hierarchical Sn3O2(OH)2 octahedra, which are self‐assembled one inside the other, resembling “Russian doll” organization, have been obtained by a metalorganic approach. This synthesis is based on the controlled hydrolysis of [Sn(NMe2)2]2 in the presence of an alkylamine ligand in an organic solvent (THF). The water content of the medium proved to be a key parameter for the formation of these multi‐walled octahedra. The resultant structures have been used as gas‐sensitive layers on micromachined silicon devices. During in situ heating, Sn3O2(OH)2 is oxidized to SnO2 while retaining the initial morphology. The sensors present outstanding dynamic responses at very low CO concentrations (7 % and 67 % resistance variation to 0.25 and 20 ppm CO, respectively, at an operating temperature of 500 °C). This superior gas‐sensing performance is closely related to the unique microstructure of the SnO2 multi‐walled octahedra. Highly sensitive CO detection: Hierarchical SnO2 structures with a “Russian doll” octahedral form have been prepared by a metalorganic route. These structures exhibit very high gas‐sensing performance compared to SnO2 made of simple nanoparticles or in the form of a thin film (see graphic). These results highlight the great potential of hierarchical multi‐walled structures for use in extremely sensitive gas sensors.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201600650