A short route to cyclopentadienyl tricarbonylrhenium substituted derivatives

CpRe(CO)(3) substituted derivatives were obtained in good yields (44-96%) from fulvenes and Re-2(CO)(10) in boiling mesitylene. This new methodology was applied to the synthesis of CpRe(CO)(3) substituted steroids with success. (C) 2002 Elsevier Science B.V. All rights reserved.

Saved in:
Bibliographic Details
Published in:Journal of organometallic chemistry 2003-02, Vol.668 (1-2), p.140-144
Main Authors: Le Bideau, F, Henique, J, Pigeon, Pascal, Joerger, Jm, Top, Siden, Jaouen, G
Format: Article
Language:English
Subjects:
Chemical Sciences
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:CpRe(CO)(3) substituted derivatives were obtained in good yields (44-96%) from fulvenes and Re-2(CO)(10) in boiling mesitylene. This new methodology was applied to the synthesis of CpRe(CO)(3) substituted steroids with success. (C) 2002 Elsevier Science B.V. All rights reserved.
ISSN:0022-328X
0022-328X
DOI:10.1016/S0022-328X(02)02090-9