Heptacoordinated Nickel(II) as an Ising-Type Anisotropic Building Unit: Illustration with a Pentanuclear [(NiL)3{W(CN)8}2] Complex

Heptacoordinated nickel(II) complexes characterized by substantial Ising-type single-ion anisotropy have been involved in the construction of two pentanuclear [Ni3W2] compounds by association with [W(CN)8]3–. For one of them, slow relaxation of magnetization was observed to occur concomitantly with...

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Bibliographic Details
Published in:Inorganic chemistry 2013-03, Vol.52 (5), p.2283-2285
Main Authors: Gogoi, Nayanmoni, Thlijeni, Mehrez, Duhayon, Carine, Sutter, Jean-Pascal
Format: Article
Language:English
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Summary:Heptacoordinated nickel(II) complexes characterized by substantial Ising-type single-ion anisotropy have been involved in the construction of two pentanuclear [Ni3W2] compounds by association with [W(CN)8]3–. For one of them, slow relaxation of magnetization was observed to occur concomitantly with antiferromagnetic ordering.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic3027368