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Experimental Densities and Speeds of Sound of Substituted Phenols and Their Modeling with the Prigogine–Flory–Patterson Model

This work provides new experimental data of speed of sound and density for seven pure components of pyrolysis bio-oil at atmospheric pressure for several phenols (phenol, o-, m-, and p-cresol), two phenolic ethers (2-methoxyphenol and eugenol) and one phenolic ester (methyl salicylate) at temperatur...

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Bibliographic Details
Published in:Journal of chemical and engineering data 2013-11, Vol.58 (11), p.2925-2931
Main Authors: Cunha, Deivisson L, Coutinho, João A. P, Daridon, Jean Luc, Reis, Rodrigo A, Paredes, Márcio L. L
Format: Article
Language:English
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Summary:This work provides new experimental data of speed of sound and density for seven pure components of pyrolysis bio-oil at atmospheric pressure for several phenols (phenol, o-, m-, and p-cresol), two phenolic ethers (2-methoxyphenol and eugenol) and one phenolic ester (methyl salicylate) at temperatures of (288.15 to 343.15) K. Densities and sound velocities are correlated with the Prigogine–Flory–Patterson (PFP) model. The properties are well described with the PFP model showing a better performance for the denser substances. The relation between density and speed of sound evidence the complex thermophysical behavior of substituted phenols.
ISSN:0021-9568
1520-5134
DOI:10.1021/je4003256