Valence photoionization and resonant core excitation of ozone - experimental and theoretical study of the C-state of O3

Resonant Auger electron spectra of core excited O3 (1s−12b11) are presented for the first time. The photoionization valence spectrum with sample purity and resolution superior to those published is presented. The first direct experimental evidence for the 2 B1 state of O3+ is found. Ab initio calcul...

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Bibliographic Details
Published in:	Chemical physics letters 2003-06, Vol.375 (1-2), p.76-83
Main Authors:	WIESNER, K, FINK, R. F, SVENSSON, S, BJÖRNEHOLM, O, SORENSEN, S. L, ANDERSSON, M, FEIFEL, R, HJELTE, I, MIRON, C, NAVES DE BRITO, A, ROSENQVIST, L, WANG, H
Format:	Article
Language:	eng
Subjects:	Atomic and molecular physics Autoionization, photoionization, and photodetachment Chemical Sciences Exact sciences and technology Molecular properties and interactions with photons or physical chemistry Photon interactions with molecules Physics Theoretical and
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Summary:	Resonant Auger electron spectra of core excited O3 (1s−12b11) are presented for the first time. The photoionization valence spectrum with sample purity and resolution superior to those published is presented. The first direct experimental evidence for the 2 B1 state of O3+ is found. Ab initio calculations of the resonant Auger electron (RAE) spectrum have been performed supporting the assignment of the -state.
ISSN:	0009-2614 1873-4448