New generation of nuclear fuels: Stability of different stearates under high doses gamma irradiation in the manufacturing process

In the future reactors, the pellets radioactivity will increase due to the modification of the plutonium concentration. The stability of the organic additive used as lubricating/deagglomerating agent has thus to be evaluated. Up to now, zinc stearate is employed, but new additives are tested in this...

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Bibliographic Details
Published in:Journal of nuclear materials 2017-07, Vol.490, p.288-298
Main Authors: Lebeau, D., Esnouf, S., Gracia, J., Audubert, F., Ferry, M.
Format: Article
Language:English
Subjects:
Dose estimation
High doses
Instantaneous gas emission rates
Nuclear Experiment
Nuclear fuel pellets
Nuclear Theory
Physics
Radio-oxidation
Radiolysis
Stearates
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Summary:In the future reactors, the pellets radioactivity will increase due to the modification of the plutonium concentration. The stability of the organic additive used as lubricating/deagglomerating agent has thus to be evaluated. Up to now, zinc stearate is employed, but new additives are tested in this study and compared to zinc stearate. In a first part of this paper, the order of magnitude of the dose deposited in the stearates has been estimated. Afterward, three different stearates have been irradiated, using gamma-rays at doses as high as 2000 kGy. Two atmospheres of irradiation were tested, i.e. inert atmosphere and air. Samples were characterized using the following analytical tools: mass spectrometry, thermogravimetry and infrared spectroscopy. The objective is the evaluation of the ageing of these materials. In the nuclear fuel pellets manufacturing context, the candidate which could replace zinc stearate, if this one is too degraded to fulfill its role of lubricant in the pellets of the future manufacturing, has been determined. •Dose deposition estimation for different stearates.•Stearates radiolysis and radio-oxidization at high doses using gamma-rays.•H2 emission estimation as a function of atmosphere and dose.•Chemical modifications in stearates as a function of atmosphere and dose.•Comparison of three stearates.
ISSN:0022-3115
1873-4820
DOI:10.1016/j.jnucmat.2017.04.029