Loading…
Thermoresponsive Starch Hydrogel Stabilized Pd Nanoparticles: Soft Catalyst for the Preparation of -[alpha]-Methylbiphenylalanine in Water Aiming at Bioorthogonal Chemistries
The corn-starch was able to reduce Pd(II) species under relatively low concentration (5.0 wt/vol) leading to the formation of a thermoresponsive palladium nanoparticles-containing hydrogel with D = 16.1 nm ± 6.4 nm. It was successfully applied to the Suzuki-Miyaura reaction step in neat water involv...
Saved in:
Published in: | Catalysis letters 2021-03, Vol.151 (3), p.844 |
---|---|
Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Summary: | The corn-starch was able to reduce Pd(II) species under relatively low concentration (5.0 wt/vol) leading to the formation of a thermoresponsive palladium nanoparticles-containing hydrogel with D = 16.1 nm ± 6.4 nm. It was successfully applied to the Suzuki-Miyaura reaction step in neat water involved in the synthesis of (±)-N-acetyl-[alpha]-methyl-4-biphenylalanine ethyl ester, a direct precursor of an unnatural quaternary biarylalanine. Graphic |
---|---|
ISSN: | 1011-372X 1572-879X |
DOI: | 10.1007/s10562-020-03350-5 |