Thermal decomposition of inclusion compounds on the base of the metal-organic framework [[Zn.sub.4].sub.4]]: part I

Inclusion compounds based on metal-organic frameworks (MOFs) have promising practical applications in gas storage, the separation, and fine purification of substances, and also in catalysis. These MOFs are crystalline compounds consisting of metal ions coordinated by bridging organic ligands with th...

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Bibliographic Details
Published in:Journal of thermal analysis and calorimetry 2014-08, Vol.117 (2), p.747
Main Authors: Logvinenko, Vladimir A, Sapchenko, Sergey A, Fedin, Vladimir P
Format: Article
Language:English
Subjects:
Benzene
Dimethylformamide
Toluene
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Summary:Inclusion compounds based on metal-organic frameworks (MOFs) have promising practical applications in gas storage, the separation, and fine purification of substances, and also in catalysis. These MOFs are crystalline compounds consisting of metal ions coordinated by bridging organic ligands with the formation of porous structures. We study the kinetic stability of two inclusion compounds on the base of the new framework: [[Zn.sub.4](dmf)[(ur).sub.2][(ndc).sub.4]]*6[C.sub.6][H.sub.6] and [[Zn.sub.4](dmf)[(ur).sub.2][(ndc).sub.4]]* 5[C.sub.6][H.sub.5]C[H.sub.3] ([ndc.sup.2-] = 2,6-naphtalenedicarboxylate, ur = hexamethylentetramin, dmf = N,N'-dimethylformamide). The inclusion compound with benzene is more stable than the compound with toluene. The reduced stability of the toluene compound may be connected with the toluene molecule's shape: the [C.sub.6][H.sub.5]C[H.sub.3] molecule is more bulky and asymmetric than the [C.sub.6][H.sub.6] molecule; the MOF matrix structure must be greatly distorted to include the toluene molecules and the compound stability decreases.
ISSN:1388-6150
1588-2926
DOI:10.1007/s10973-014-3827-y