Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions

Bis-protic N-heterocyclic carbene complexes of platinum and palladium (4) yield dimeric structures 6 when treated with sodium tert-butoxide in CH2Cl2. The use of a more polar solvent (THF) and a strong base (LiN(iPr)2) gave the lithium chloride adducts monobasic complex 7 or analogous dibasic comple...

Full description

Bibliographic Details

Published in:	Beilstein journal of organic chemistry 2016-06, Vol.12 (1), p.1334-1339
Main Authors:	Marelius, David C, Moore, Curtis E, Rheingold, Arnold L, Grotjahn, Douglas B
Format:	Article
Language:	eng
Subjects:	15N NMR spectroscopy Chemistry Full Research Paper NHC palladium platinum protic N-heterocyclic carbene
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!