Poly(L-Cysteine) Modified Pencil Graphite Electrode for Determination of Sunset Yellow in Food and Beverage Samples by Differential Pulse Voltammetry

In this study, we have focused on the use of a poly(L-cysteine) (PLC) modified pencil graphite electrode (PGE) as a sensor for determination of Sunset Yellow (SY). The performance of the modified electrode was studied using cyclic voltammetric and differential pulse voltammetric method. The modified...

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Bibliographic Details
Published in:International journal of electrochemical science 2018-01, Vol.13 (1), p.159-174
Main Authors: Koyun, Ozge, Sahin, Yucel
Format: Article
Language:English
Subjects:
Electropolymerization
Food Additive
Pencil Graphite Electrode
Poly(L-cysteine)
Sunset yellow
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Summary:In this study, we have focused on the use of a poly(L-cysteine) (PLC) modified pencil graphite electrode (PGE) as a sensor for determination of Sunset Yellow (SY). The performance of the modified electrode was studied using cyclic voltammetric and differential pulse voltammetric method. The modified electrode was characterized by electrochemical impedance spectroscopy, cyclic voltammetry and Fourier transform infrared spectroscopy. The surface of the modified electrode was examined by scanning electron microscope. The electrochemical behavior of SY in phosphate buffer solution (pH 7.0) was examined using unmodified PGE and PLC modified PGE (PLC/PGE). The results showed that the electrochemical response of PLC/PGE to SY was significantly developed. The PLC/PGE showed linear responses in the electrochemical oxidation of SY between the concentration values of 1.0 µM and 1000 µM. The sensor (PLC/PGE) showed a good response for SY with a detection limit of 0.125 µM (S/N=3). Analytical application of PLC/PGE was successfully tested in the determination of SY in food and beverage samples.
ISSN:1452-3981
1452-3981
DOI:10.20964/2018.01.40