Efficient generation of polarization-entangled photons in metal-organic framework waveguides

Parametric nonlinear optical processes are instrumental in optical quantum technology for generating entangled light. However, the range of materials conventionally used for producing entangled photons is limited. Metal-organic frameworks (MOFs) have emerged as a novel class of optical materials wit...

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Bibliographic Details
Published in:Optics express 2024-08, Vol.32 (17), p.29514
Main Authors: Paiva, Simón, Fritz, Rubén A., Raj, Sanoj, Colón, Yamil J., Herrera, Felipe
Format: Article
Language:English
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Summary:Parametric nonlinear optical processes are instrumental in optical quantum technology for generating entangled light. However, the range of materials conventionally used for producing entangled photons is limited. Metal-organic frameworks (MOFs) have emerged as a novel class of optical materials with customizable nonlinear properties and proven chemical and optical stability. The large number of combinations of metal atoms and organic ligand from which bulk MOF crystals are known to form, facilitates the search of promising candidates for nonlinear optics. To accelerate the discovery of next-generation quantum light sources, we employ a multi-scale modeling approach to study phase-matching conditions for collinear degenerate type-II spontaneous parametric down conversion (SPDC) with MOF-based one dimensional waveguides. Using periodic-density-functional theory calculations to compute the nonlinear optical properties of selected zinc-based MOF crystals, we predict polarization-entangled pair generation rates of order 10 4 − 10 7 s −1 mW −1 at 1064 nm for 10 mm crystals, improving the brightness of industry materials such as PPKTP and BBO in some cases. This work underscores the great potential of MOF single crystals as entangled light sources for applications in quantum communication and sensing.
ISSN:1094-4087
1094-4087
DOI:10.1364/OE.532747