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High Rate Capability of All-Solid-State Lithium Batteries Using Quasi-Solid-State Electrolytes Containing Ionic Liquids
Here we demonstrate a high rate capability of all-solid-state lithium batteries using quasi-solid-state electrolytes containing an ionic liquid. We fabricated solid-state electrolyte using an ionic liquid: 1 mol l−1 lithium bis(fluorosulfonyl) imide dissolved 1-Ethyl-3-methylimidazolium bis(fluorosu...
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Published in: | Journal of the Electrochemical Society 2020-02, Vol.167 (4), p.40511 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Here we demonstrate a high rate capability of all-solid-state lithium batteries using quasi-solid-state electrolytes containing an ionic liquid. We fabricated solid-state electrolyte using an ionic liquid: 1 mol l−1 lithium bis(fluorosulfonyl) imide dissolved 1-Ethyl-3-methylimidazolium bis(fluorosulfonyl)imide (LiFSI/EMI-FSI) and fumed silica nanoparticles with a variety of volume fractions. The fabricated freestanding film with 85% volume fraction of LiFSI/EMI-FSI exhibited an ionic conductivity and self-diffusion coefficient of lithium-containing species; 10.2 mS cm−1 and 3.3 × 10−11 m2 s−1 at 35 °C. We revealed that the increase in the volume fraction of the LiFSI/EMI-FSI led to the decrease in concentration polarization resistance, leading to an enhanced rate capability in Li LiFePO4 batteries. The fabricated Li LiFePO4 batteries using freestanding electrolyte films with 85 vol% LiFSI/EMI-FSI exhibited a high capacity (>150 mAh g−1) at 1 C (0.6 mA cm−2) based on that at 0.1 C. Further, we fabricated bipolar-type all-solid-state lithium batteries assembled by stacking of Li LiFePO4 cell components in a single package. The bipolar-type lithium batteries exhibited the increased packing energy density, depending on the number of stacked cells. These results open opportunities of designing all-solid-state lithium batteries for high energy and power density using quasi-solid-state electrolytes. |
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ISSN: | 0013-4651 1945-7111 |
DOI: | 10.1149/1945-7111/ab743d |