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Dipole moments and quantum chemical study of the structure of furan-containing gem-bromonitroethenes
As shown by the dipole moment method and quantum chemical calculations, 1-(furan-2-yl)-2-nitroethene and 1-nitro-2-(5-nitrofuran-2-yl)ethenes exist in solution as E - s - trans isomers while 1-bromo-2- (5-bromofuran-2-yl)-1-nitroethene and 1-bromo-1-nitro-2-(5-nitrofuran-2-yl)ethene have Z - s - cis...
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Published in: | Russian journal of organic chemistry 2015-09, Vol.51 (9), p.1282-1285 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | As shown by the dipole moment method and quantum chemical calculations, 1-(furan-2-yl)-2-nitroethene and 1-nitro-2-(5-nitrofuran-2-yl)ethenes exist in solution as
E
-
s
-
trans
isomers while 1-bromo-2- (5-bromofuran-2-yl)-1-nitroethene and 1-bromo-1-nitro-2-(5-nitrofuran-2-yl)ethene have
Z
-
s
-
cis
configuration. |
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ISSN: | 1070-4280 1608-3393 |
DOI: | 10.1134/S1070428015090122 |