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Dipole moments and quantum chemical study of the structure of furan-containing gem-bromonitroethenes

As shown by the dipole moment method and quantum chemical calculations, 1-(furan-2-yl)-2-nitroethene and 1-nitro-2-(5-nitrofuran-2-yl)ethenes exist in solution as E - s - trans isomers while 1-bromo-2- (5-bromofuran-2-yl)-1-nitroethene and 1-bromo-1-nitro-2-(5-nitrofuran-2-yl)ethene have Z - s - cis...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2015-09, Vol.51 (9), p.1282-1285
Main Authors: Vereshchagina, Ya. A., Chachkov, D. V., Khanafieva, R. R., Alimova, A. Z., Berestovitskaya, V. M., Makarenko, S. V., Eliseenko, S. S.
Format: Article
Language:English
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Summary:As shown by the dipole moment method and quantum chemical calculations, 1-(furan-2-yl)-2-nitroethene and 1-nitro-2-(5-nitrofuran-2-yl)ethenes exist in solution as E - s - trans isomers while 1-bromo-2- (5-bromofuran-2-yl)-1-nitroethene and 1-bromo-1-nitro-2-(5-nitrofuran-2-yl)ethene have Z - s - cis configuration.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428015090122