Chiral Bis(oxazoline)palladium(II) Complexes With 2,2′-methylenebis(4S,5R)-4,5-diphenyl-2-oxazoline as Ligand

Chiral bis(oxazoline)palladium(II) complexes Pd[(4S,5R)-mbd poxo]Cl 2 ·2MeCN (1) and Pd[(4S, 5R)-mbdpoxo](MeCN) 2 (SbF 6 ) 2 (2) were synthesized ((4S,5R)-mbdpoxo = 2,2′-methylenebis (4S,5R)-4,5-diphenyl-2-oxazoline) and characterized by elemental analysis, IR, 1 H, and 13 C NMR spectra. The structu...

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Bibliographic Details
Published in:Inorganic and nano-metal chemistry 2014-02, Vol.44 (2), p.208-211
Main Authors: Xu, Hong-Wu, Zhang, Liu-Xue, Li, Jin-Xia
Format: Article
Language:English
Subjects:
bis(oxazoline)
Chemical analysis
chiral
NMR
Nuclear magnetic resonance
Palladium
palladium(II) complex
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Summary:Chiral bis(oxazoline)palladium(II) complexes Pd[(4S,5R)-mbd poxo]Cl 2 ·2MeCN (1) and Pd[(4S, 5R)-mbdpoxo](MeCN) 2 (SbF 6 ) 2 (2) were synthesized ((4S,5R)-mbdpoxo = 2,2′-methylenebis (4S,5R)-4,5-diphenyl-2-oxazoline) and characterized by elemental analysis, IR, 1 H, and 13 C NMR spectra. The structure of complex 1 was determined by X-ray diffraction and the results show that it crystallizes in monoclinic space group P2 1 with a = 11.6278(16) Å, b = 8.2371(7) Å, c = 17.825(2) Å, β = 99.037(14)°, V = 1686.1(4) Å 3 and Z = 2.
ISSN:1553-3174
2470-1556
1553-3182
2470-1564
DOI:10.1080/15533174.2013.769589