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Attempts to Synthesize Unsymmetrical Sodium 1,2-Diphosphacyclopentadienides

The first attempt to synthesize nonsymmetric sodium 1,2-diphosphacyclopenta- dienides was made on the basis of reaction of cyclopropenylium bromides with tertiary phosphines and following treatment of cyclopropenyl phosphonium salts with sodium polyphosphides.

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2015-06, Vol.190 (5-6), p.863-865
Main Authors: Kochetkova, Liliya, Bezkishko, Il'ya, Miluykov, Vasili, Sinyashin, Oleg
Format: Article
Language:English
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Summary:The first attempt to synthesize nonsymmetric sodium 1,2-diphosphacyclopenta- dienides was made on the basis of reaction of cyclopropenylium bromides with tertiary phosphines and following treatment of cyclopropenyl phosphonium salts with sodium polyphosphides.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426507.2014.989434