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Synthesis of Sedamine by Cycloisomerisation of an Allenic Hydroxylamine
ABSTRACT Isoxazolidines have been prepared in a stereoselective manner by treatment of allenic hydroxylamines with silver(I). This methodology has been used in a short synthesis of the alkaloid (+)-sedamine.
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Published in: | Synthesis (Stuttgart) 2008-04, Vol.2008 (7), p.1033-1038 |
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Main Authors: | , , |
Format: | Article |
Language: | English |
Citations: | Items that cite this one |
Online Access: | Get full text |
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Summary: | ABSTRACT
Isoxazolidines have been prepared in a stereoselective manner by treatment of allenic hydroxylamines with silver(I). This methodology has been used in a short synthesis of the alkaloid (+)-sedamine. |
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ISSN: | 0039-7881 1437-210X |
DOI: | 10.1055/s-2008-1066985 |