Heck Arylations of Baylis-Hillman Adducts

Abstract This short review examines the palladium-catalyzed arylation of the C=C bond of Baylis-Hillman adducts. It summarizes the different intermolecular and intramolecular reaction procedures, and contains detailed tables making it easier to compare their efficiency. 1 Introduction 2 Intermolecul...

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Bibliographic Details
Published in:Synthesis (Stuttgart) 2011-11, Vol.2011 (22), p.3581-3591
Main Authors: Le Bras, Jean, Muzart, Jacques
Format: Article
Language:English
Subjects:
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Preparations and properties
review
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Summary:Abstract This short review examines the palladium-catalyzed arylation of the C=C bond of Baylis-Hillman adducts. It summarizes the different intermolecular and intramolecular reaction procedures, and contains detailed tables making it easier to compare their efficiency. 1 Introduction 2 Intermolecular Reactions 2.1 Without Decarboxylation 2.2 With Decarboxylation 3 Intramolecular Reactions 4 Conclusions
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0030-1260240