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A terpyridine-appended hexaarylbenzene fluorophore: synthesis, photophysical properties and application for the colorimetric detection of Fe 2+ in aqueous solution
The hexaarylbenzene (HAB)-based push–pull fluorophore HAB-MeO-TPy with the 2,2′:6′,2″-terpyridine (TPy) unit as an acceptor and the methoxy (MeO) group as a donor was developed. It was observed that HAB-MeO-TPy exhibited an unusual uphill-type emission with increasing solvent polarity from cyclohexa...
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Published in: | New journal of chemistry 2023-02, Vol.47 (9), p.4245-4251 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Citations: | Items that this one cites |
Online Access: | Get full text |
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Summary: | The hexaarylbenzene (HAB)-based push–pull fluorophore HAB-MeO-TPy with the 2,2′:6′,2″-terpyridine (TPy) unit as an acceptor and the methoxy (MeO) group as a donor was developed. It was observed that HAB-MeO-TPy exhibited an unusual uphill-type emission with increasing solvent polarity from cyclohexane to DMSO. By comparison with a previously reported fluorophore HPB-MeO-DCV, a structure–property relationship regarding this uncommon fluorescence behavior was disclosed. Furthermore, the sensing properties of HAB-MeO-TPy for metal ions were also investigated. In the presence of Fe
2+
, HAB-MeO-TPy displayed a visual color change from colorless to magenta, indicating that HAB-MeO-TPy can act as a “naked eye” sensor for Fe
2+
detection. From absorption titration experiments, the detection limit was determined to be 1.50 × 10
−7
M. In addition, HAB-MeO-TPy was successfully applied to detect Fe
2+
in real water samples. |
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ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/D2NJ05821A |