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Thermocatalytic formic acid dehydrogenation: recent advances and emerging trends
As a state-of-the-art resource for in situ hydrogen supply, formic acid has recently attracted considerable attention due to its advantages of high hydrogen content, low toxicity, and easy storage and transportation. However, generating hydrogen from formic acid in a controlled manner under mild con...
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Published in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2021-11, Vol.9 (43), p.24241-2426 |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | As a state-of-the-art resource for
in situ
hydrogen supply, formic acid has recently attracted considerable attention due to its advantages of high hydrogen content, low toxicity, and easy storage and transportation. However, generating hydrogen from formic acid in a controlled manner under mild conditions is still challenging. The stability of formic acid dehydrogenation (FAD) catalysts and CO selectivity require further investigation. With this in mind, recent advances in heterogeneous catalysts, homogeneous catalysts, and carbon-based supports are summarized. After that, a perspective on catalyst design (the size-sensitivity effect, core-shell catalysts, single-atom catalysts, and metal-organic framework-derived catalysts), mechanism clarification, and microchannel reactor construction is proposed for effectively propelling the development of FAD. This perspective aims at not only providing innovative ideas for fundamental research in FAD, but also promoting the applications of
in situ
hydrogen supply obtained from formic acid.
As a state-of-the-art resource for
in situ
hydrogen supply, formic acid has recently attracted considerable attention due to its advantages of high hydrogen content, low toxicity, and easy storage and transportation. |
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ISSN: | 2050-7488 2050-7496 |
DOI: | 10.1039/d1ta05910f |