Recent advances in acyl radical enabled reactions between aldehydes and alkenes

Radical-mediated functionalization of alkenes has been emerging as an elegant and straightforward protocol to increase molecule complexity. Moreover, the abstraction of a hydrogen atom from aldehydes to afford acyl radicals has evolved as a rising star due to its high atom-economy and the ready avai...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (5), p.6111-612
Main Authors: Liu, Yi-Lin, Ouyang, Yue-Jun, Zheng, Hongxing, Liu, Hongxin, Wei, Wen-Ting
Format: Article
Language:English
Subjects:
Aldehydes
Alkenes
Radicals
Stellar evolution
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Radical-mediated functionalization of alkenes has been emerging as an elegant and straightforward protocol to increase molecule complexity. Moreover, the abstraction of a hydrogen atom from aldehydes to afford acyl radicals has evolved as a rising star due to its high atom-economy and the ready availability of aldehydes. Considering the great influence and synthetic potential of acyl radical enabled reactions between aldehydes and alkenes, we provide a summary of the state of the art in this field with a specific emphasis on the working models and corresponding mechanisms. The discussion is divided according to the kind of alkenes and reaction type. Acyl radical enabled reactions between aldehydes and alkenes.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc02112e