Laser-induced chemical transformation of free-standing graphene oxide membranes in liquid and gas ammonia environments

Laser-induced chemical conversion of graphene oxide (GO) is an effective way to modify its properties and expand its potential use for numerous applications. In this work, a mechanically stable and flexible free-standing GO membrane is synthesized and further processed by ultraviolet laser radiation...

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Bibliographic Details
Published in:RSC advances 2016-01, Vol.6 (55), p.534-542
Main Authors: Pérez del Pino, A, György, E, Cotet, C, Baia, L, Logofatu, C
Format: Article
Language:English
Subjects:
Deoxygenation
Graphene
Irradiation
Liquids
Membranes
Morphology
Nanostructure
Oxides
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Summary:Laser-induced chemical conversion of graphene oxide (GO) is an effective way to modify its properties and expand its potential use for numerous applications. In this work, a mechanically stable and flexible free-standing GO membrane is synthesized and further processed by ultraviolet laser radiation in gas and liquid ammonia-rich environments. Electron and atomic force microscopy, as well as X-ray photoelectron spectroscopy analysis, reveal that laser irradiation in gas leads to a large defect-induced morphology modification and high deoxygenation process, accompanied by the slight incorporation of nitrogen functionality to the reduced GO structure. Conversely, irradiation in liquid provokes significant integration of nitrogen groups, essentially amines, into a partially reduced GO structure, without evident modification of the morphology. Electrical measurements on the macro- and nano-scale point to a complex contribution of morphology and oxidized regions to the overall resistance of the rGO. A fast and versatile method is developed for laser-induced reduction and nitrogen doping of free-standing graphene oxide membranes.
ISSN:2046-2069
2046-2069
DOI:10.1039/c6ra07109k