The use of reduced copper metal-organic frameworks to facilitate CuAAC click chemistry

A reduced copper metal-organic framework (rCu-MOF) containing Cu ions was prepared by reducing raw MOFs (Cu-BTC). A series of polymer functionalizations and coupling reactions could subsequently be achieved via CuAAC click chemistry, thus demonstrating the high activity, facile recyclability and goo...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (82), p.12226-12229
Main Authors: Fu, Q, Xie, K, Tan, S, Ren, J M, Zhao, Q, Webley, P A, Qiao, G G
Format: Article
Language:English
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Summary:A reduced copper metal-organic framework (rCu-MOF) containing Cu ions was prepared by reducing raw MOFs (Cu-BTC). A series of polymer functionalizations and coupling reactions could subsequently be achieved via CuAAC click chemistry, thus demonstrating the high activity, facile recyclability and good structural stability of rCu-MOFs for catalytic applications.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc06890a