Preparation and Analysis of Bicyclic Polystyrene

Bicyclic polystyrene was prepared by combining atom transfer radical polymerization and click chemistry. The bicyclic polymer was separated from concurrently produced acyclic (branched) polymers through fractional precipitation, and its purity was quantified by two-dimensional liquid chromatography...

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Bibliographic Details
Published in:Macromolecules 2014-06, Vol.47 (12), p.3791-3796
Main Authors: Jeong, Jonghwa, Kim, Kihyun, Lee, Rooda, Lee, Sookyeong, Kim, Hyewon, Jung, Haeji, Kadir, Mohammad Abdul, Jang, Yujin, Jeon, Heung Bae, Matyjaszewski, Krzysztof, Chang, Taihyun, Paik, Hyun-jong
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
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Summary:Bicyclic polystyrene was prepared by combining atom transfer radical polymerization and click chemistry. The bicyclic polymer was separated from concurrently produced acyclic (branched) polymers through fractional precipitation, and its purity was quantified by two-dimensional liquid chromatography analysis. The structure of bicyclic polymer was characterized by SEC, MALDI–TOF MS, 1H NMR, and FT-IR.
ISSN:0024-9297
1520-5835
DOI:10.1021/ma500391z