Preparation and Reactivity of O 2-Sulfonated Diazeniumdiolates

We report the facile preparation of O 2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O 2-substituted diazeniumdiolates available for potential applications in research and medicine.

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Bibliographic Details
Published in:Journal of organic chemistry 2003-01, Vol.68 (2), p.656-657
Main Authors: D'Sa, Raechelle A, Wang, Yuhong, Ruane, Patrick H, Showalter, Brett M, Saavedra, Joseph E, Davies, Keith M, Citro, Michael L, Booth, Melissa N, Keefer, Larry K, Toscano, John P
Format: Article
Language:English
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Summary:We report the facile preparation of O 2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O 2-substituted diazeniumdiolates available for potential applications in research and medicine.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo026656n