Spontaneous Resolution in the Ionothermal Synthesis of Homochiral Zn(II) Metal–Organic Frameworks with (10,3)-a Topology Constructed from Achiral 5-Sulfoisophthalate

Spontaneous Resolution in the Ionothermal Synthesis of Homochiral Zn(II) Metal–Organic Frameworks with (10,3)-a Topology Constructed from Achiral 5-Sulfoisophthalate

Two homochiral enantiomers {(EMIM)[Zn(SIP)(IM)]} n (1a and 1b, EMIM = 1-ethyl-3-methylimidazolium) possessing chiral (10,3)-a topology constructed from an achiral rigid 5-sulfoisophthalate (SIP) ligand and imidazole (IM) have been obtained by spontaneous resolution under ionothermal conditions. The...

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Bibliographic Details
Published in:Crystal growth & design 2011-09, Vol.11 (9), p.3717-3720
Main Authors: Liu, Qing-Yan, Wang, Yu-Ling, Zhang, Na, Jiang, Yun-Liang, Wei, Jia-Jia, Luo, Feng
Format: Article
Language:eng
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Summary:Two homochiral enantiomers {(EMIM)[Zn(SIP)(IM)]} n (1a and 1b, EMIM = 1-ethyl-3-methylimidazolium) possessing chiral (10,3)-a topology constructed from an achiral rigid 5-sulfoisophthalate (SIP) ligand and imidazole (IM) have been obtained by spontaneous resolution under ionothermal conditions. The homochiral enantiomers show second-order nonlinear optical effects and photoluminescence.
ISSN:1528-7483
1528-7505