Microstructural Understanding of the Length- and Stiffness-Dependent Shear Thinning in Semidilute Colloidal Rods

Complex fluids containing low concentrations of slender colloidal rods can display a high viscosity, while little flow is needed to thin the fluid. This feature makes slender rods essential constituents in industrial applications and biology. Though this behavior strongly depends on the rod-length,...

Full description

Saved in:
Bibliographic Details
Published in:Macromolecules 2019-12, Vol.52 (24), p.9604-9612
Main Authors: Lang, Christian, Kohlbrecher, Joachim, Porcar, Lionel, Radulescu, Aurel, Sellinghoff, Karin, Dhont, Jan Karel George, Lettinga, Minne Paul
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Complex fluids containing low concentrations of slender colloidal rods can display a high viscosity, while little flow is needed to thin the fluid. This feature makes slender rods essential constituents in industrial applications and biology. Though this behavior strongly depends on the rod-length, so far no direct relation could be identified. We employ a library of filamentous viruses to study the effect of rod size and flexibility on the zero-shear viscosity and shear-thinning behavior. Rheology and small-angle neutron scattering data are compared to a revised version of the standard theory for ideally stiff rods, which incorporates a complete shear-induced dilation of the confinement. While the earlier predicted length-independent prefactor of the restricted rotational diffusion coefficient is confirmed by varying the length and concentration of the rods, the revised theory correctly predicts the shear-thinning behavior as well as the underlying orientational order. These results can be directly applied to understand the manifold systems based on rodlike colloids and design new materials.
ISSN:0024-9297
1520-5835
DOI:10.1021/acs.macromol.9b01592