Novel Ag/Au Nanocubes Modified the Negative/Positive Charge on the Surface and Their Application in Surface-Enhanced Raman Scattering

Bimetallic nanostructures have received considerable attention in recent years due to their widespread use in applications such as photonics, catalysis and surface-enhanced Raman scattering (SERS) detection. In this work, a simple and effective strategy has been developed to synthesize Ag/Au@negativ...

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Bibliographic Details
Published in:	Procedia CIRP 2016, Vol.40, p.551-556
Main Authors:	Quyen, Tran Thi Bich, Hwang, Bing-Joe
Format:	Article
Language:	eng
Subjects:	Ag/Au bimetallic nanocubes (Ag/Au NCBs) Ag/Au@NH3+ and Ag/Au@COO− NCBs negative charge positive charge Rhodamine 6G (R6G) SERS
Online Access:	Get full text
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Summary:	Bimetallic nanostructures have received considerable attention in recent years due to their widespread use in applications such as photonics, catalysis and surface-enhanced Raman scattering (SERS) detection. In this work, a simple and effective strategy has been developed to synthesize Ag/Au@negative(COO−)-Ag/Au@positive(NH3+) charge on the nanocubes’ (with hollow or porous structures) surfaces, based on a galvanic replacement reaction and co-reduction method of the corresponding ions. The prepared bimetallic Ag/Au@NH3+-Ag/Au@COO− nanocubes have been characterized by UV–vis, TEM, and XRD. Our results show that the SERS technique is able to detect R6G within wide concentration range, i.e. 10-16 – 10-8 M, with lower limit of detection (LOD) being 10-16 M. It demonstrates that the Ag/Au@NH3+-Ag/Au@COO− nanocubes have potential applications in SERS for the detection of biomolecules or dye molecules.
ISSN:	2212-8271 2212-8271