Recent advances in schiff base metal complexes derived from 4-aminoantipyrine derivatives and their potential applications

•Different types of schiff base metal complexes derived from 4-aminoantipyrine were reviewed.•Used to evaluate the detection of Phenol, H2O2, Al(III),Cr(III), Cu(II), Fe(II), F–etc., from the industrial effluent in very low concentration through visible and fluorescent method.•Wide application in ma...

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Published in:Journal of molecular structure 2020-12, Vol.1222, p.128885, Article 128885
Main Authors: Sakthivel, A., Jeyasubramanian, K., Thangagiri, B., Raja, J. Dhaveethu
Format: Article
Language:eng
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Summary:•Different types of schiff base metal complexes derived from 4-aminoantipyrine were reviewed.•Used to evaluate the detection of Phenol, H2O2, Al(III),Cr(III), Cu(II), Fe(II), F–etc., from the industrial effluent in very low concentration through visible and fluorescent method.•Wide application in materials science such as corrosion inhibition and electrode material in solar cell components.•Most prominent biological applications like antimicrobial activities, antioxidant, anti-inflammatory activity and cytotoxicity, DNA binding and cleavage studies were compiled. In this review, the importance of 4-aminoantipyrine (4-AAP) and its derivatives after forming a Schiff base by condensing with different kinds of carbonyl compounds and their metal complexes are described. As it is a well-known fact that the Schiff base is able to form metal complexes with almost all transition metals and lanthanides, many researchers have elaborately studied the use of 4-AAP derivatives and their complexes in various applications. Owing to the facile chelating ability, it is extensively used to identify and to estimate the presence of metal ions in solutions. Besides the use of 4-AAP derivatives in analytical chemistry, the metal chelates are extensively used in the fields like corrosion inhibition, energy harvesting, antimicrobial, anti-inflammatory, antioxidant, cytotoxicity, anti-convulsant, anthelmintic activity, analgesic, antipyretic, DNA binding and DNA cleavage, etc. The prominent results available in these fields are compiled in this review. [Display omitted]
ISSN:0022-2860
1872-8014