A microporous [Ni 3(μ 3-OH)] cluster-based framework with 9-connected ncb topology

A microporous [Ni 3(μ 3-OH)] cluster-based framework with 9-connected ncb topology

A porous metal organic framework [Ni IIINi II 2( μ 3-OH)(bdc) 1.5(int) 3] n x(solvents) ( 1: bdc = 1,4-benzenedicarboxylate; int = isonicotinate) based on the trinuclear Ni 3( μ 3-OH) units was solvothermally synthesized and structurally characterized. It features a three-dimensional 9-connected ncb...

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Bibliographic Details
Published in:Inorganic chemistry communications 2011-10, Vol.14 (10), p.1588-1590
Main Authors: Yang, E., Liu, Zi-Sheng, Lin, Shen, Chen, Shun-Yu
Format: Article
Language:eng
Subjects:
Crystal structure
Gas sorption
Isonicotinate
Solvothermal synthesis
Topology
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Summary:A porous metal organic framework [Ni IIINi II 2( μ 3-OH)(bdc) 1.5(int) 3] n x(solvents) ( 1: bdc = 1,4-benzenedicarboxylate; int = isonicotinate) based on the trinuclear Ni 3( μ 3-OH) units was solvothermally synthesized and structurally characterized. It features a three-dimensional 9-connected ncb-type framework with two kinds of cage substructures and large one-dimensional channels. Both N 2 and CO 2 gas sorption studies of 1 were investigated to demonstrate the permanent porosity in 1. A microporous metal organic framework with 9-connected ncb topology is constructed from the trinuclear Ni 3( μ 3-OH) units and shows gas sorption properties. [Display omitted] ► Synthesis and structure of a microporous [Ni 3(μ 3-OH)] cluster-based framework ► Nine-connected ncb topology in metal organic framework ► A microporous metal organic framework with N 2 and CO 2 gas sorption properties
ISSN:1387-7003
1879-0259