Rapid and controllable synthesis of Fe3O4 octahedral nanocrystals embedded-reduced graphene oxide using microwave irradiation for high performance lithium-ion batteries

We present a facile and simple method for the large-scale synthesis of octahedral iron oxide nanocrystals (Fe3O4 ONCs) on the reduced graphene oxide nanosheets (rGO NSs). The Fe3O4-ONCs embedded on the rGO NSs surfaces (Fe3O4-ONCs@rGO hybrids) are synthesized by microwave assisted. The Fe3O4 nanopar...

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Bibliographic Details
Published in:	Electrochimica acta 2018-08, Vol.281, p.78-87
Main Authors:	Kumar, Rajesh, Singh, Rajesh K., Alaferdov, Andrei V., Moshkalev, Stanislav A.
Format:	Article
Language:	eng
Subjects:	Embedded structure Lithium ion storage Microwave Octahedral Fe3O4 nanocrystals Reduced graphene oxide
Online Access:	Get full text
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Summary:	We present a facile and simple method for the large-scale synthesis of octahedral iron oxide nanocrystals (Fe3O4 ONCs) on the reduced graphene oxide nanosheets (rGO NSs). The Fe3O4-ONCs embedded on the rGO NSs surfaces (Fe3O4-ONCs@rGO hybrids) are synthesized by microwave assisted. The Fe3O4 nanoparticles (Fe3O4 NPs) decorated rGO NSs (Fe3O4-NPs@rGO hybrids) are also synthesized using same method for comparative studies in lithium ion storage. During the synthesis process, rGO NSs served as the structural platform to embed the positively charged Fe3O4-ONCs on the basis of the electrostatic assembly followed by the microwave reduction of rGO NSs. Compared to Fe3O4-NPs@rGO, Fe3O4-ONCs@rGO hybrids shows superior electrochemical performance, including better cycling stability and rate performances, which may be attributed to the embedded structure of the nano-size Fe3O4-ONCs in rGO NSs. The electrochemical performances of the hybrids material as anode for lithium storage are evaluated by cyclic voltammetry and constant current charging and discharging. The synthesized Fe3O4-ONCs@rGO hybrids exhibited high lithium storage capacity, outstanding cycling stability (540 mAh g−1 after 120 cycles at 100 mA g−1). This low-cost and fast synthesis strategy may be employed in other embedded structured hybrids design for high-performance lithium batteries. [Display omitted] •The Fe3O4 –ONCs nanocrystals embedded into rGO NSs were synthesized.•The rGO NSs served as the structural platform for Fe3O4-ONCs.•The Fe3O4-ONCs@rGO hybrid shows superior electrochemical performance.•The Fe3O4-ONCs@rGO hybrid shows good lithium storage and cycling stability.
ISSN:	0013-4686 1873-3859