Pre-stabilized reduced graphene oxide by ammonia as carrier for Ni(OH)2 with excellent electrochemical property
An advanced electrochemical pseudocapacitor material based on reduced graphene oxide and nickel hydroxide (rGO&Ni(OH) 2 ) was prepared by an easy process where ammonia acted as a pre-stabilizer that could be easily removed. The results showed that the agglomeration and re-stacking of rGO could b...
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Published in: | Journal of solid state electrochemistry 2015, Vol.19 (1), p.229-239 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | eng |
Subjects: | |
Online Access: | Get full text |
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Summary: | An advanced electrochemical pseudocapacitor material based on reduced graphene oxide and nickel hydroxide (rGO&Ni(OH)
2
) was prepared by an easy process where ammonia acted as a pre-stabilizer that could be easily removed. The results showed that the agglomeration and re-stacking of rGO could be effectively prevented, resulting in few-layer rGO nanosheet with high specific surface area of 891.22 m
2
/g which could supply large available area for loading nanoparticle. After the incorporation of Ni(OH)
2
nanoparticle, the rGO&Ni(OH)
2
composite owned excellent electrochemical performance thanks to effective prevention of agglomeration and re-stacking of rGO with large size of the sp
2
domain, no residual of pre-stabilizer of ammonia, and tight contact between rGO and Ni(OH)
2
. Specifically, the rGO&Ni(OH)
2
electrode exhibited excellent stability at scan rates from 100 to 300 mV/s. A high specific capacitance of 1,008 F/g was obtained at high current density of 42 A/g in 6 mol/L KOH aqueous electrolyte, and the specific capacitance demonstrated good rate capability. Moreover, rGO&Ni(OH)
2
electrode showed a long cycle life, retaining 74 % specific capacitance after 2,000 cycles at current density of 6 A/g. The advantages of easy process and excellent electrochemical property suggested great potential application of rGO&Ni(OH)
2
in supercapacitors.
Graphical Abstract
An advanced electrochemical pseudocapacitor material based on reduced graphene oxide and nickel hydroxide was prepared by an easy process where ammonia acted as a pre-stabilizer that could be easily removed. The obtained material owned excellent electrochemical property, including high capacitance, good rate capability, excellent stability, long cycle life, etc. |
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ISSN: | 1432-8488 1433-0768 |