Oil‐Water Separation Using a Self‐Cleaning Underwater Superoleophobic Micro/Nanowire Hierarchical Nanostructured Membrane

In this study, we fabricated a novel micro/nanowire hierarchical membrane with flexible, self‐cleaning and underwater superoleophobic properties for efficient oil‐water separation under vacuum filtration. This novel membrane composed of ultralong copper microwires (MW) and functional TiO2 nanowires...

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Bibliographic Details
Published in:ChemistrySelect (Weinheim) 2016-05, Vol.1 (7), p.1329-1338
Main Authors: Tan, Benny Yong Liang, Liu, Zhaoyang, Gao, Peng, Tai, Ming Hang, Sun, Darren Delai
Format: Article
Language:English
Subjects:
copper microwire
copper microwires
flexible membrane
Oil-water separation
oil/water separation membrane
self cleaning
TiO2 nanowire
titanium dioxide nanowires
vacuum-driven, flexible
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Summary:In this study, we fabricated a novel micro/nanowire hierarchical membrane with flexible, self‐cleaning and underwater superoleophobic properties for efficient oil‐water separation under vacuum filtration. This novel membrane composed of ultralong copper microwires (MW) and functional TiO2 nanowires (NW). The ultralong copper microwires act as a scaffold, as well as providing mechanical flexibility for the membrane, which allow it to be operated under vacuum‐driven condition. Meanwhile, underwater superoleophobic TiO2 nanowires membrane provides nano‐ scale pore size, ensuring the filtration of smaller oil droplets under vacuum condition. Moreover, the possession of the self‐cleaning function of TiO2 nanowires allows the degradation of foulants and contaminants under UV irradiation, which promote the facile recovery of the used membrane. Clearly, the employment of this novel membrane can be considered as a practical option for efficient oil‐water separations. This study demonstrates the discovery of a novel TiO2/ Copper micro/nanowire hierachical (TC) membrane built with flexible and underwater superoleophobic properties for efficient oil‐water separation under vacuum filtration. Furthermore, the possession of the self‐cleaning function of TiO2 nanowires allows the degradation of foulants and contaminants under UV irradiation, which promote the facile recovery of the used membrane. Ultimately, this membrane illustrated promising potential for numerous application relating to oily wastewater treatment.
ISSN:2365-6549
2365-6549
DOI:10.1002/slct.201600141