(Aryl)(phosphanyl)Carbene: Ground- and Excited-State Reactions

Cyclopropanation, carbene coupling, and photolytically induced 1,2‐migration reactions are reported for the stable singlet [bis(diisopropylamino)phosphanyl][o,o′‐bis(trifluoromethyl)phenyl]carbene (1). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

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Bibliographic Details
Published in:European journal of organic chemistry 2003-06, Vol.2003 (11), p.2039-2042
Main Authors: Despagnet-Ayoub, Emmanuelle, Gornitzka, Heinz, Bourissou, Didier, Bertrand, Guy
Format: Article
Language:English
Subjects:
Carbenes
Cycloaddition
Diastereoselectivity
Photolysis
Sigmatropic rearrangement
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Summary:Cyclopropanation, carbene coupling, and photolytically induced 1,2‐migration reactions are reported for the stable singlet [bis(diisopropylamino)phosphanyl][o,o′‐bis(trifluoromethyl)phenyl]carbene (1). (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200200657