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A Room-Temperature Route to Bismuth Nanotube Arrays
A room‐temperature aqueous‐chemical route has been developed to synthesize a high proportion (above 80%) of bamboo‐raft‐like bismuth nanotube arrays using bismuth chloride and metallic zinc powder as reagents. The prepared Bi nanotubes have uniform diameters of approximately 3−5 nm and lengths from...
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Published in: | European journal of inorganic chemistry 2003-10, Vol.2003 (20), p.3699-3702 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A room‐temperature aqueous‐chemical route has been developed to synthesize a high proportion (above 80%) of bamboo‐raft‐like bismuth nanotube arrays using bismuth chloride and metallic zinc powder as reagents. The prepared Bi nanotubes have uniform diameters of approximately 3−5 nm and lengths from several hundred nanometers to several micrometers. HRTEM observations show that the axial direction of the prepared nanotubes is along the normal direction of the (012) lattice planes of the rhombohedral bismuth. The possible formation mechanism is discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003) |
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ISSN: | 1434-1948 1099-0682 |
DOI: | 10.1002/ejic.200300347 |