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Frontispiece: Short Total Synthesis of (±)‐γ‐Lycorane by a Sequential Intramolecular Acylal Cyclisation (IAC) and Intramolecular Heck Addition Reaction
The pentacyclic structure of the natural product (±)‐γ‐lycorane was synthesized by a new sequential Lewis acid mediated intramolecular acylal cyclisation (IAC)/Heck coupling approach. A range of bicyclic heterocycles was also synthesized by using this methodology in good yields demonstrating the pot...
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Published in: | Chemistry : a European journal 2017-04, Vol.23 (20), p.n/a |
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Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Online Access: | Get full text |
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Summary: | The pentacyclic structure of the natural product (±)‐γ‐lycorane was synthesized by a new sequential Lewis acid mediated intramolecular acylal cyclisation (IAC)/Heck coupling approach. A range of bicyclic heterocycles was also synthesized by using this methodology in good yields demonstrating the potential of the IAC reaction to access complex heterocycles. For more details, see the Communication by S. Hilton et al. on page 4750 ff. |
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ISSN: | 0947-6539 1521-3765 |
DOI: | 10.1002/chem.201782062 |