A breathing chiral molecular solid for enantioseparation via single-crystal-to-single-crystal transformation

Two chiral supramolecular porous solids derived from novel cluster-based structures of [Mn^Ⅲ_4Mn^Ⅱ] and [Mn_7^Ⅲ Mn_3^Ⅱ ] were synthesized. Driven by the distinct pores and host-guest interactions, they exhibited either selective gas adsorption ability for the former or the ability of enan- tioselect...

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Bibliographic Details
Published in:中国科学通报：英文版 2015 (4), p.447-452
Main Author: Jun-Liang Liu Wei Liu Guo-Zhang Huang Ming-Liang Tong
Format: Article
Language:English
Subjects:
分子固体
单晶
吸附能力
呼吸
多孔固体
手性
相互作用
超分子
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Summary:Two chiral supramolecular porous solids derived from novel cluster-based structures of [Mn^Ⅲ_4Mn^Ⅱ] and [Mn_7^Ⅲ Mn_3^Ⅱ ] were synthesized. Driven by the distinct pores and host-guest interactions, they exhibited either selective gas adsorption ability for the former or the ability of enan- tioselective separation via reversible single-crystal-to-sin- gle-crystal transformation for the latter.
ISSN:1001-6538
1861-9541