Continuous flow ozonolysis using atmospheric plasma
Ozonolysis is widely used in organic synthesis to obtain aldehydes and ketones from alkenes, a process of great interest, for example, for the pharmaceutical industry. This reaction is more environmentally accepted than other alternative oxidations and it has good atom efficiency. Ozonolysis, howeve...
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rr-article-95559022012-01-01T00:00:00Z Continuous flow ozonolysis using atmospheric plasma Carlos Castello Beltran (7165145) Benjamin R. Buckley (1299393) Felipe Iza (1258965) Mechanical engineering not elsewhere classified untagged Mechanical Engineering not elsewhere classified Ozonolysis is widely used in organic synthesis to obtain aldehydes and ketones from alkenes, a process of great interest, for example, for the pharmaceutical industry. This reaction is more environmentally accepted than other alternative oxidations and it has good atom efficiency. Ozonolysis, however, has an important drawback; the ozonides generated as intermediates in the process are unstable and pose a risk of explosion. To minimize this risk, continuous flow processing can be used, as this eliminates the accumulation of large amounts of hazardous intermediates, thereby offering an alternative to batch processing that greatly enhances the control and safety of the ozonolysis process.1,2 Here we report on the results obtained with an air plasma-driven continuous-flow ozonolysis system. (... continues) 2012-01-01T00:00:00Z Text Conference contribution 2134/17568 https://figshare.com/articles/conference_contribution/Continuous_flow_ozonolysis_using_atmospheric_plasma/9555902 CC BY-NC-ND 4.0 |
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Mechanical engineering not elsewhere classified untagged Mechanical Engineering not elsewhere classified Carlos Castello Beltran Benjamin R. Buckley Felipe Iza Continuous flow ozonolysis using atmospheric plasma |
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Ozonolysis is widely used in organic synthesis to obtain aldehydes and ketones from alkenes, a process of great interest, for example, for the pharmaceutical industry. This reaction is more environmentally accepted than other alternative oxidations and it has good atom efficiency. Ozonolysis, however, has an important drawback; the ozonides generated as intermediates in the process are unstable and pose a risk of explosion. To minimize this risk, continuous flow processing can be used, as this eliminates the accumulation of large amounts of hazardous intermediates, thereby offering an alternative to batch processing that greatly enhances the control and safety of the ozonolysis process.1,2 Here we report on the results obtained with an air plasma-driven continuous-flow ozonolysis system. (... continues) |
format |
Default Conference proceeding |
author |
Carlos Castello Beltran Benjamin R. Buckley Felipe Iza |
author_facet |
Carlos Castello Beltran Benjamin R. Buckley Felipe Iza |
author_sort |
Carlos Castello Beltran (7165145) |
title |
Continuous flow ozonolysis using atmospheric plasma |
title_short |
Continuous flow ozonolysis using atmospheric plasma |
title_full |
Continuous flow ozonolysis using atmospheric plasma |
title_fullStr |
Continuous flow ozonolysis using atmospheric plasma |
title_full_unstemmed |
Continuous flow ozonolysis using atmospheric plasma |
title_sort |
continuous flow ozonolysis using atmospheric plasma |
publishDate |
2012 |
url |
https://hdl.handle.net/2134/17568 |
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1797918576582066176 |