Dinuclear palladium(II) and platinum(II) complexes of a readily accessible bicyclic diphosphane

Dinuclear palladium(II) and platinum(II) complexes of a readily accessible bicyclic diphosphane

The one-step synthesis (33 % isolated yield) of a novel bicyclic diphosphane, [P(CH2)2NC6H4(4-NMe2)]2, P−P(NMe2), from the reaction of [P(CH2OH)4]Cl and H2NC6H4(4-NMe2) in methanol is described. Surprisingly, P−P(NMe2) displays excellent air/solution stability (towards H2O, CH3OH) and can also funct...

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Bibliographic Details
Main Authors: Mark Edgar, Mark Elsegood, Pingchuan Liu, Christopher R Miles, Martin Smith, Shimeng Wu
Format: Default Article
Published: 2022
Subjects:
Inorganic chemistry not elsewhere classified
Bridging ligands
Late-transition metals
P-P diphosphanes
Protonation
X-ray diffraction
Chemistry
Inorganic Chemistry
Online Access:https://hdl.handle.net/2134/20038649.v1
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https://hdl.handle.net/2134/20038649.v1

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