A library of atomically thin metal chalcogenides

Investigations of two-dimensional transition-metal chalcogenides (TMCs) have recently revealed interesting physical phenomena, including the quantum spin Hall effect , valley polarization and two-dimensional superconductivity , suggesting potential applications for functional devices . However, of t...

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Bibliographic Details
Published in:	Nature (London) 2018-04, Vol.556 (7701), p.355-359
Main Authors:	Zhou, Jiadong, Lin, Junhao, Huang, Xiangwei, Zhou, Yao, Chen, Yu, Xia, Juan, Wang, Hong, Xie, Yu, Yu, Huimei, Lei, Jincheng, Wu, Di, Liu, Fucai, Fu, Qundong, Zeng, Qingsheng, Hsu, Chuang-Han, Yang, Changli, Lu, Li, Yu, Ting, Shen, Zexiang, Lin, Hsin, Yakobson, Boris I, Liu, Qian, Suenaga, Kazu, Liu, Guangtong, Liu, Zheng
Format:	Article
Language:	eng
Subjects:	Alloys Analysis Ceramic powders Chalcogenides Chemical properties Chemical synthesis Chemical vapor deposition Fourier transforms Growth rate Hafnium Hall effect Iron Libraries Low temperature Melting Melting point Melting points Metal compounds Metal oxides Metals Metals (Materials) Molybdenum disulfide Monolayers Niobium Organic chemistry Palladium Platinum Polarization (spin alignment) Powders (Particulate matter) Quantum Hall effect R&D Research & development Resveratrol Salts Science & Technology - Other Topics Spectrum analysis Sulfurization Superconductivity Superconductors Tantalum Titanium Transition metal compounds Transition metals Tungsten disulfide Zirconium
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Summary:	Investigations of two-dimensional transition-metal chalcogenides (TMCs) have recently revealed interesting physical phenomena, including the quantum spin Hall effect , valley polarization and two-dimensional superconductivity , suggesting potential applications for functional devices . However, of the numerous compounds available, only a handful, such as Mo- and W-based TMCs, have been synthesized, typically via sulfurization , selenization and tellurization of metals and metal compounds. Many TMCs are difficult to produce because of the high melting points of their metal and metal oxide precursors. Molten-salt-assisted methods have been used to produce ceramic powders at relatively low temperature and this approach was recently employed to facilitate the growth of monolayer WS and WSe . Here we demonstrate that molten-salt-assisted chemical vapour deposition can be broadly applied for the synthesis of a wide variety of two-dimensional (atomically thin) TMCs. We synthesized 47 compounds, including 32 binary compounds (based on the transition metals Ti, Zr, Hf, V, Nb, Ta, Mo, W, Re, Pt, Pd and Fe), 13 alloys (including 11 ternary, one quaternary and one quinary), and two heterostructured compounds. We elaborate how the salt decreases the melting point of the reactants and facilitates the formation of intermediate products, increasing the overall reaction rate. Most of the synthesized materials in our library are useful, as supported by evidence of superconductivity in our monolayer NbSe and MoTe samples and of high mobilities in MoS and ReS . Although the quality of some of the materials still requires development, our work opens up opportunities for studying the properties and potential application of a wide variety of two-dimensional TMCs.
ISSN:	0028-0836 1476-4687