Chemo-Marangoni convection driven by an interfacial reaction: Pattern formation and kinetics

A combined study devoted to chemo-Marangoni convection and the underlying kinetics is presented for a biphasic system in which surfactants are produced in situ by an interfacial reaction. The pattern formation studied in a Hele-Shaw cell in both microgravity and terrestrial environments initially sh...

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Bibliographic Details
Published in:Chaos (Woodbury, N.Y.) N.Y.), 2012-09, Vol.22 (3), p.037112-037112
Main Authors: Eckert, K., Acker, M., Tadmouri, R., Pimienta, V.
Format: Article
Language:English
Subjects:
Chemical Sciences
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Summary:A combined study devoted to chemo-Marangoni convection and the underlying kinetics is presented for a biphasic system in which surfactants are produced in situ by an interfacial reaction. The pattern formation studied in a Hele-Shaw cell in both microgravity and terrestrial environments initially shows an ensemble of chemo-Marangoni cells along a nearly planar interface. Soon, a crossover occurs to periodic large-scale interfacial deformations which coexist with the Marangoni cells. This crossover can be correlated with the autocatalytic nature of the interfacial reaction identified in the kinetic studies. The drastic increase in the product concentration is associated with an enhanced aggregate-assisted transfer after the critical micellar concentration is approached. In this context, it was possible to conclusively explain the changes in the periodicity of the interfacial deformations depending on the reactant concentration ratio.
ISSN:1054-1500
1089-7682
DOI:10.1063/1.4742844