Loading…
Electrochemical cell for neutron reflectometry studies of the structureof ionic liquids at electrified interface
We describe the design and use of a closed three-electrode electrochemical cell for neutron reflectometry studies of the structure of the electrical double-layer in ionic liquids. A transparent glass counter electrode was incorporated to allow easy monitoring of any gas bubbles trapped in the cell....
Saved in:
| Published in: | Review of scientific instruments 2010-07, Vol.81 (7), p.074101-074101-6 |
|---|---|
| Main Authors: | , , , , , |
| Format: | Article |
| Language: | |
| Citations: | Items that this one cites |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | cdi_FETCH-scitation_primary_10_1063_1_3455178Electrochemical_cell3 |
| container_end_page | 074101-6 |
| container_issue | 7 |
| container_start_page | 074101 |
| container_title | Review of scientific instruments |
| container_volume | 81 |
| creator | Lauw, Y. Rodopoulos, T. Gross, M. Nelson, A. Gardner, R. Horne, M. D. |
| description | We describe the design and use of a closed three-electrode electrochemical cell for neutron reflectometry studies of the structure of the electrical double-layer in ionic liquids. A transparent glass counter electrode was incorporated to allow easy monitoring of any gas bubbles trapped in the cell. A 100 mm diameter silicon wafer polished to 0.1 nm rms roughness coated with gold over a chromium adhesion layer was used as the working electrode. The utility of the cell was demonstrated during neutron reflectometry measurements of the ultrahigh purity ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
(
[
C
4
mpyr
]
[
NTf
2
]
)
at two different applied potentials. |
| doi_str_mv | 10.1063/1.3455178 |
| format | article |
| fullrecord | <record><control><sourceid>scitation</sourceid><recordid>TN_cdi_scitation_primary_10_1063_1_3455178Electrochemical_cell</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>rsi</sourcerecordid><originalsourceid>FETCH-scitation_primary_10_1063_1_3455178Electrochemical_cell3</originalsourceid><addsrcrecordid>eNqlj71OxDAQhC0EEuGg4A32BXLYOH80NOgQD0BvWc5at8iJj7Vd3NvjoKtomWY0q9WnGSEeldwrOegntddd36txuhKNktNLOw7P-lo0UuquHcZuuhV3KX3Jql6pRpwOAV3m6I64kLMBHIYAPjKsWOp9BUa_vcQFM58h5TITJoge8hFr5OJyYayZ4koOAn0XmhPYDPiLJk84A60Z2VuH9-LG25Dw4eI78fp--Hz7aJOjbHOFmBPTYvlslDTbJqPMZdOfrmbrqv8N-AGuQ2S2</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Electrochemical cell for neutron reflectometry studies of the structureof ionic liquids at electrified interface</title><source>American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list)</source><source>AIP Journals (American Institute of Physics)</source><creator>Lauw, Y. ; Rodopoulos, T. ; Gross, M. ; Nelson, A. ; Gardner, R. ; Horne, M. D.</creator><creatorcontrib>Lauw, Y. ; Rodopoulos, T. ; Gross, M. ; Nelson, A. ; Gardner, R. ; Horne, M. D.</creatorcontrib><description>We describe the design and use of a closed three-electrode electrochemical cell for neutron reflectometry studies of the structure of the electrical double-layer in ionic liquids. A transparent glass counter electrode was incorporated to allow easy monitoring of any gas bubbles trapped in the cell. A 100 mm diameter silicon wafer polished to 0.1 nm rms roughness coated with gold over a chromium adhesion layer was used as the working electrode. The utility of the cell was demonstrated during neutron reflectometry measurements of the ultrahigh purity ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
(
[
C
4
mpyr
]
[
NTf
2
]
)
at two different applied potentials.</description><identifier>ISSN: 0034-6748</identifier><identifier>EISSN: 1089-7623</identifier><identifier>DOI: 10.1063/1.3455178</identifier><identifier>CODEN: RSINAK</identifier><publisher>American Institute of Physics</publisher><ispartof>Review of scientific instruments, 2010-07, Vol.81 (7), p.074101-074101-6</ispartof><rights>2010 American Institute of Physics</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-scitation_primary_10_1063_1_3455178Electrochemical_cell3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/rsi/article-lookup/doi/10.1063/1.3455178$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>315,786,788,790,801,27957,27958,76741</link.rule.ids></links><search><creatorcontrib>Lauw, Y.</creatorcontrib><creatorcontrib>Rodopoulos, T.</creatorcontrib><creatorcontrib>Gross, M.</creatorcontrib><creatorcontrib>Nelson, A.</creatorcontrib><creatorcontrib>Gardner, R.</creatorcontrib><creatorcontrib>Horne, M. D.</creatorcontrib><title>Electrochemical cell for neutron reflectometry studies of the structureof ionic liquids at electrified interface</title><title>Review of scientific instruments</title><description>We describe the design and use of a closed three-electrode electrochemical cell for neutron reflectometry studies of the structure of the electrical double-layer in ionic liquids. A transparent glass counter electrode was incorporated to allow easy monitoring of any gas bubbles trapped in the cell. A 100 mm diameter silicon wafer polished to 0.1 nm rms roughness coated with gold over a chromium adhesion layer was used as the working electrode. The utility of the cell was demonstrated during neutron reflectometry measurements of the ultrahigh purity ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
(
[
C
4
mpyr
]
[
NTf
2
]
)
at two different applied potentials.</description><issn>0034-6748</issn><issn>1089-7623</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqlj71OxDAQhC0EEuGg4A32BXLYOH80NOgQD0BvWc5at8iJj7Vd3NvjoKtomWY0q9WnGSEeldwrOegntddd36txuhKNktNLOw7P-lo0UuquHcZuuhV3KX3Jql6pRpwOAV3m6I64kLMBHIYAPjKsWOp9BUa_vcQFM58h5TITJoge8hFr5OJyYayZ4koOAn0XmhPYDPiLJk84A60Z2VuH9-LG25Dw4eI78fp--Hz7aJOjbHOFmBPTYvlslDTbJqPMZdOfrmbrqv8N-AGuQ2S2</recordid><startdate>20100728</startdate><enddate>20100728</enddate><creator>Lauw, Y.</creator><creator>Rodopoulos, T.</creator><creator>Gross, M.</creator><creator>Nelson, A.</creator><creator>Gardner, R.</creator><creator>Horne, M. D.</creator><general>American Institute of Physics</general><scope/></search><sort><creationdate>20100728</creationdate><title>Electrochemical cell for neutron reflectometry studies of the structureof ionic liquids at electrified interface</title><author>Lauw, Y. ; Rodopoulos, T. ; Gross, M. ; Nelson, A. ; Gardner, R. ; Horne, M. D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-scitation_primary_10_1063_1_3455178Electrochemical_cell3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lauw, Y.</creatorcontrib><creatorcontrib>Rodopoulos, T.</creatorcontrib><creatorcontrib>Gross, M.</creatorcontrib><creatorcontrib>Nelson, A.</creatorcontrib><creatorcontrib>Gardner, R.</creatorcontrib><creatorcontrib>Horne, M. D.</creatorcontrib><jtitle>Review of scientific instruments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lauw, Y.</au><au>Rodopoulos, T.</au><au>Gross, M.</au><au>Nelson, A.</au><au>Gardner, R.</au><au>Horne, M. D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical cell for neutron reflectometry studies of the structureof ionic liquids at electrified interface</atitle><jtitle>Review of scientific instruments</jtitle><date>2010-07-28</date><risdate>2010</risdate><volume>81</volume><issue>7</issue><spage>074101</spage><epage>074101-6</epage><pages>074101-074101-6</pages><issn>0034-6748</issn><eissn>1089-7623</eissn><coden>RSINAK</coden><abstract>We describe the design and use of a closed three-electrode electrochemical cell for neutron reflectometry studies of the structure of the electrical double-layer in ionic liquids. A transparent glass counter electrode was incorporated to allow easy monitoring of any gas bubbles trapped in the cell. A 100 mm diameter silicon wafer polished to 0.1 nm rms roughness coated with gold over a chromium adhesion layer was used as the working electrode. The utility of the cell was demonstrated during neutron reflectometry measurements of the ultrahigh purity ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
(
[
C
4
mpyr
]
[
NTf
2
]
)
at two different applied potentials.</abstract><pub>American Institute of Physics</pub><doi>10.1063/1.3455178</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0034-6748 |
| ispartof | Review of scientific instruments, 2010-07, Vol.81 (7), p.074101-074101-6 |
| issn | 0034-6748 1089-7623 |
| language | |
| recordid | cdi_scitation_primary_10_1063_1_3455178Electrochemical_cell |
| source | American Institute of Physics:Jisc Collections:Transitional Journals Agreement 2021-23 (Reading list); AIP Journals (American Institute of Physics) |
| title | Electrochemical cell for neutron reflectometry studies of the structureof ionic liquids at electrified interface |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-21T18%3A04%3A46IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-scitation&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrochemical%20cell%20for%20neutron%20reflectometry%20studies%20of%20the%20structureof%20ionic%20liquids%20at%20electrified%20interface&rft.jtitle=Review%20of%20scientific%20instruments&rft.au=Lauw,%20Y.&rft.date=2010-07-28&rft.volume=81&rft.issue=7&rft.spage=074101&rft.epage=074101-6&rft.pages=074101-074101-6&rft.issn=0034-6748&rft.eissn=1089-7623&rft.coden=RSINAK&rft_id=info:doi/10.1063/1.3455178&rft_dat=%3Cscitation%3Ersi%3C/scitation%3E%3Cgrp_id%3Ecdi_FETCH-scitation_primary_10_1063_1_3455178Electrochemical_cell3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |