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Luminescence-structure relationships in solids doped with Bi
The luminescence properties of Bi 3+ in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function, he , involved in one of the m...
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| Published in: | Physical chemistry chemical physics : PCCP 2023-04, Vol.25 (16), p.1127-1154 |
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| container_end_page | 1154 |
| container_issue | 16 |
| container_start_page | 1127 |
| container_title | Physical chemistry chemical physics : PCCP |
| container_volume | 25 |
| creator | Boutinaud, Philippe |
| description | The luminescence properties of Bi
3+
in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function,
he
, involved in one of the models is described step-by-step for an easy implementation in a home-made calculator or machine-learning algorithm. Finally, a criterion based on the experimental value of the Stokes shift is introduced to help in fixing the origin of the Bi
3+
-related emission.
The
1
S
0
→
3
P
1
transition energy of Bi
3+
in solids is predicted within ±0.35 eV. |
| doi_str_mv | 10.1039/d3cp00289f |
| format | article |
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3+
in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function,
he
, involved in one of the models is described step-by-step for an easy implementation in a home-made calculator or machine-learning algorithm. Finally, a criterion based on the experimental value of the Stokes shift is introduced to help in fixing the origin of the Bi
3+
-related emission.
The
1
S
0
→
3
P
1
transition energy of Bi
3+
in solids is predicted within ±0.35 eV.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/d3cp00289f</identifier><ispartof>Physical chemistry chemical physics : PCCP, 2023-04, Vol.25 (16), p.1127-1154</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Boutinaud, Philippe</creatorcontrib><title>Luminescence-structure relationships in solids doped with Bi</title><title>Physical chemistry chemical physics : PCCP</title><description>The luminescence properties of Bi
3+
in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function,
he
, involved in one of the models is described step-by-step for an easy implementation in a home-made calculator or machine-learning algorithm. Finally, a criterion based on the experimental value of the Stokes shift is introduced to help in fixing the origin of the Bi
3+
-related emission.
The
1
S
0
→
3
P
1
transition energy of Bi
3+
in solids is predicted within ±0.35 eV.</description><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpFj01LxDAUAIMouK5evAv5A9WXvLRNwIsufkHBg96XbN4LG-m2JWkR_70HRU8zp4ER4lLBtQJ0N4RhAtDWxSOxUqbByoE1x3_eNqfirJQPAFC1wpW47ZZDGrgEHgJXZc5LmJfMMnPv5zQOZZ-mItMgy9gnKpLGiUl-pnkv79O5OIm-L3zxy7V4e3x43zxX3evTy-auq7LTc2U1a4wQUDvd7DgS7LwhboxGIrJtTa0hYy27YDVoZlBtG3Xta0Q2Edfi6qeaS9hOOR18_tr-j-I3LmhHbw</recordid><startdate>20230426</startdate><enddate>20230426</enddate><creator>Boutinaud, Philippe</creator><scope/></search><sort><creationdate>20230426</creationdate><title>Luminescence-structure relationships in solids doped with Bi</title><author>Boutinaud, Philippe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r92t-82e23f0c32926befd0ba4de6423ddd875d74d488e9c8202ee0177f25a533e4f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2023</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boutinaud, Philippe</creatorcontrib><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Boutinaud, Philippe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Luminescence-structure relationships in solids doped with Bi</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><date>2023-04-26</date><risdate>2023</risdate><volume>25</volume><issue>16</issue><spage>1127</spage><epage>1154</epage><pages>1127-1154</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><notes>12</notes><notes>and NaYF</notes><notes>in CaF</notes><notes>Philippe Boutinaud received his PhD degree in Sept. 1991 from the University of Bordeaux, France, after 2 years spent in the laboratory of Paul Hagenmüller; then he moved to the Department of chemical physics of the University of Geneva, Switzerland, as a research assistant. He got a permanent position as an associate professor in Sept. 1994 at the Laboratory of Inorganic Materials, University of Clermont-Ferrand, France, received his habilitation in Feb. 1997 and was promoted as full professor two years later. His research activity focuses on luminescent materials with specific interest on structure-luminescence relationships and metal-to-metal charge transfer processes.</notes><notes>Al</notes><notes>See DOI</notes><notes>Electronic supplementary information (ESI) available: The handmade step-by-step calculation of</notes><notes>O</notes><notes>Cs</notes><notes>2</notes><notes>3</notes><notes>https://doi.org/10.1039/d3cp00289f</notes><notes>4</notes><notes>5</notes><notes>NaYX</notes><notes>6</notes><notes>YPO</notes><notes>Y</notes><notes>(X = Cl, Br), YAlO</notes><notes>he</notes><abstract>The luminescence properties of Bi
3+
in 177 inorganic compounds are reviewed and rationalized based on two simple and easy-to-use models. These models are applicable to any kind of compound whose crystal structure is known. The calculation of the nephelauxetic function,
he
, involved in one of the models is described step-by-step for an easy implementation in a home-made calculator or machine-learning algorithm. Finally, a criterion based on the experimental value of the Stokes shift is introduced to help in fixing the origin of the Bi
3+
-related emission.
The
1
S
0
→
3
P
1
transition energy of Bi
3+
in solids is predicted within ±0.35 eV.</abstract><doi>10.1039/d3cp00289f</doi><tpages>28</tpages></addata></record> |
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| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2023-04, Vol.25 (16), p.1127-1154 |
| issn | 1463-9076 1463-9084 |
| language | |
| recordid | cdi_rsc_primary_d3cp00289f |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| title | Luminescence-structure relationships in solids doped with Bi |
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