Loading…
Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations
The optical properties including optical absorption and photoluminescence (PL) properties of hybrid materials are always required to be regulated to cater for different requirements. Herein, the crystal and electronic structures of hybrid haloplumbates were adjusted to regulate the optical propertie...
Saved in:
| Published in: | CrystEngComm 2023-12, Vol.25 (47), p.6556-6567 |
|---|---|
| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | cdi_FETCH-LOGICAL-c240t-7bcb45f73986aa67986766516f89a18aea91951383f17692b5229cefd28d42173 |
| container_end_page | 6567 |
| container_issue | 47 |
| container_start_page | 6556 |
| container_title | CrystEngComm |
| container_volume | 25 |
| creator | Gao, Cheng-Cheng Tang, Xue-Na Miao, Jing-Ling Li, Yu Li, Cuncheng Liu, Guang-Ning |
| description | The optical properties including optical absorption and photoluminescence (PL) properties of hybrid materials are always required to be regulated to cater for different requirements. Herein, the crystal and electronic structures of hybrid haloplumbates were adjusted to regulate the optical properties by employing two series of well-designed structure directing agents (SDAs). Alkylated benzothiazole (btz)- and triphenylphosphine (PPh
3
)-derivative SDAs direct the formation of six new hybrid bromoplumbates, namely (Mebtz)PbBr
3
(
1
, Me = methyl), (Etbtz)PbBr
3
(
2
, Et = ethyl), (Prbtz)Pb
3
Br
8
(
3
, Pr =
n
-propyl), (MePPh
3
)PbBr
3
(
4
), (EtPPh
3
)PbBr
3
(
5
) and (PrPPh
3
)PbBr
3
(
6
). Their bromoplumbate anions all show 1D chain-like structures formed by PbBr
6
octahedra but with different connection modes. The six hybrid materials possess obvious blue or red shifted band gaps compared with inorganic PbBr
2
due to their different structural features. Their PL emission colors realize rational regulation ranging from bluish green to orange.
Different alkylated benzothiazole and triphenylphosphine cations are used to adjust the optical absorption and photoluminescence properties of inorganic-organic hybrid bromoplumbates. |
| doi_str_mv | 10.1039/d3ce00931a |
| format | article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d3ce00931a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2896682603</sourcerecordid><originalsourceid>FETCH-LOGICAL-c240t-7bcb45f73986aa67986766516f89a18aea91951383f17692b5229cefd28d42173</originalsourceid><addsrcrecordid>eNpNkctOwzAQRS0EEqWwYY9kiR0i4Efi2EtUykOqAPFYR47jtC5pHGxHKD_C9-K2CNjMjDxnfO07ABxjdIERFZcVVRohQbHcASOcMpZwROnuv3ofHHi_RAinGKMR-HrW876RwbRzGBYaKjf4IBso2wrqRqvgbGsU9MH1KvRO-03HdsGoSHXOdtoFE49tDRdD6UwFS2dXtmv6VSlDbHyasICyeR-iiq7gwzl8SaB18ClRtg3StGtpGWfiIxRUMdrWH4K9WjZeH_3kMXi7mb5O7pLZ4-395GqWKJKikOSlKtOszqngTEqWx5QzlmFWcyExl1oKLDJMOa1xzgQpM0KE0nVFeJUSnNMxON3eG3_y0WsfiqXtXRslC8IFY5yw6NkYnG0p5az3TtdF58xKuqHAqFj7XlzTyXTj-1WET7aw8-qX-9sL_QYvdYE7</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2896682603</pqid></control><display><type>article</type><title>Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Gao, Cheng-Cheng ; Tang, Xue-Na ; Miao, Jing-Ling ; Li, Yu ; Li, Cuncheng ; Liu, Guang-Ning</creator><creatorcontrib>Gao, Cheng-Cheng ; Tang, Xue-Na ; Miao, Jing-Ling ; Li, Yu ; Li, Cuncheng ; Liu, Guang-Ning</creatorcontrib><description>The optical properties including optical absorption and photoluminescence (PL) properties of hybrid materials are always required to be regulated to cater for different requirements. Herein, the crystal and electronic structures of hybrid haloplumbates were adjusted to regulate the optical properties by employing two series of well-designed structure directing agents (SDAs). Alkylated benzothiazole (btz)- and triphenylphosphine (PPh
3
)-derivative SDAs direct the formation of six new hybrid bromoplumbates, namely (Mebtz)PbBr
3
(
1
, Me = methyl), (Etbtz)PbBr
3
(
2
, Et = ethyl), (Prbtz)Pb
3
Br
8
(
3
, Pr =
n
-propyl), (MePPh
3
)PbBr
3
(
4
), (EtPPh
3
)PbBr
3
(
5
) and (PrPPh
3
)PbBr
3
(
6
). Their bromoplumbate anions all show 1D chain-like structures formed by PbBr
6
octahedra but with different connection modes. The six hybrid materials possess obvious blue or red shifted band gaps compared with inorganic PbBr
2
due to their different structural features. Their PL emission colors realize rational regulation ranging from bluish green to orange.
Different alkylated benzothiazole and triphenylphosphine cations are used to adjust the optical absorption and photoluminescence properties of inorganic-organic hybrid bromoplumbates.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d3ce00931a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alkylation ; Crystal structure ; Optical properties ; Photoluminescence</subject><ispartof>CrystEngComm, 2023-12, Vol.25 (47), p.6556-6567</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-7bcb45f73986aa67986766516f89a18aea91951383f17692b5229cefd28d42173</cites><orcidid>0000-0001-6998-9476 ; 0000-0003-1456-9858</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Gao, Cheng-Cheng</creatorcontrib><creatorcontrib>Tang, Xue-Na</creatorcontrib><creatorcontrib>Miao, Jing-Ling</creatorcontrib><creatorcontrib>Li, Yu</creatorcontrib><creatorcontrib>Li, Cuncheng</creatorcontrib><creatorcontrib>Liu, Guang-Ning</creatorcontrib><title>Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations</title><title>CrystEngComm</title><description>The optical properties including optical absorption and photoluminescence (PL) properties of hybrid materials are always required to be regulated to cater for different requirements. Herein, the crystal and electronic structures of hybrid haloplumbates were adjusted to regulate the optical properties by employing two series of well-designed structure directing agents (SDAs). Alkylated benzothiazole (btz)- and triphenylphosphine (PPh
3
)-derivative SDAs direct the formation of six new hybrid bromoplumbates, namely (Mebtz)PbBr
3
(
1
, Me = methyl), (Etbtz)PbBr
3
(
2
, Et = ethyl), (Prbtz)Pb
3
Br
8
(
3
, Pr =
n
-propyl), (MePPh
3
)PbBr
3
(
4
), (EtPPh
3
)PbBr
3
(
5
) and (PrPPh
3
)PbBr
3
(
6
). Their bromoplumbate anions all show 1D chain-like structures formed by PbBr
6
octahedra but with different connection modes. The six hybrid materials possess obvious blue or red shifted band gaps compared with inorganic PbBr
2
due to their different structural features. Their PL emission colors realize rational regulation ranging from bluish green to orange.
Different alkylated benzothiazole and triphenylphosphine cations are used to adjust the optical absorption and photoluminescence properties of inorganic-organic hybrid bromoplumbates.</description><subject>Alkylation</subject><subject>Crystal structure</subject><subject>Optical properties</subject><subject>Photoluminescence</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNpNkctOwzAQRS0EEqWwYY9kiR0i4Efi2EtUykOqAPFYR47jtC5pHGxHKD_C9-K2CNjMjDxnfO07ABxjdIERFZcVVRohQbHcASOcMpZwROnuv3ofHHi_RAinGKMR-HrW876RwbRzGBYaKjf4IBso2wrqRqvgbGsU9MH1KvRO-03HdsGoSHXOdtoFE49tDRdD6UwFS2dXtmv6VSlDbHyasICyeR-iiq7gwzl8SaB18ClRtg3StGtpGWfiIxRUMdrWH4K9WjZeH_3kMXi7mb5O7pLZ4-395GqWKJKikOSlKtOszqngTEqWx5QzlmFWcyExl1oKLDJMOa1xzgQpM0KE0nVFeJUSnNMxON3eG3_y0WsfiqXtXRslC8IFY5yw6NkYnG0p5az3TtdF58xKuqHAqFj7XlzTyXTj-1WET7aw8-qX-9sL_QYvdYE7</recordid><startdate>20231204</startdate><enddate>20231204</enddate><creator>Gao, Cheng-Cheng</creator><creator>Tang, Xue-Na</creator><creator>Miao, Jing-Ling</creator><creator>Li, Yu</creator><creator>Li, Cuncheng</creator><creator>Liu, Guang-Ning</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-6998-9476</orcidid><orcidid>https://orcid.org/0000-0003-1456-9858</orcidid></search><sort><creationdate>20231204</creationdate><title>Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations</title><author>Gao, Cheng-Cheng ; Tang, Xue-Na ; Miao, Jing-Ling ; Li, Yu ; Li, Cuncheng ; Liu, Guang-Ning</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-7bcb45f73986aa67986766516f89a18aea91951383f17692b5229cefd28d42173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Alkylation</topic><topic>Crystal structure</topic><topic>Optical properties</topic><topic>Photoluminescence</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Cheng-Cheng</creatorcontrib><creatorcontrib>Tang, Xue-Na</creatorcontrib><creatorcontrib>Miao, Jing-Ling</creatorcontrib><creatorcontrib>Li, Yu</creatorcontrib><creatorcontrib>Li, Cuncheng</creatorcontrib><creatorcontrib>Liu, Guang-Ning</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Cheng-Cheng</au><au>Tang, Xue-Na</au><au>Miao, Jing-Ling</au><au>Li, Yu</au><au>Li, Cuncheng</au><au>Liu, Guang-Ning</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations</atitle><jtitle>CrystEngComm</jtitle><date>2023-12-04</date><risdate>2023</risdate><volume>25</volume><issue>47</issue><spage>6556</spage><epage>6567</epage><pages>6556-6567</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><notes>for</notes><notes>For ESI and crystallographic data in CIF or other electronic format see DOI</notes><notes>1-6</notes><notes>Electronic supplementary information (ESI) available: Materials and characterization details, preparation details, selected bond distances and angles, additional structural figures, IR spectra, PXRD patterns, Hirshfeld surfaces, 2D fingerprint plots and band structures. CCDC</notes><notes>https://doi.org/10.1039/d3ce00931a</notes><notes>2296329-2296334</notes><abstract>The optical properties including optical absorption and photoluminescence (PL) properties of hybrid materials are always required to be regulated to cater for different requirements. Herein, the crystal and electronic structures of hybrid haloplumbates were adjusted to regulate the optical properties by employing two series of well-designed structure directing agents (SDAs). Alkylated benzothiazole (btz)- and triphenylphosphine (PPh
3
)-derivative SDAs direct the formation of six new hybrid bromoplumbates, namely (Mebtz)PbBr
3
(
1
, Me = methyl), (Etbtz)PbBr
3
(
2
, Et = ethyl), (Prbtz)Pb
3
Br
8
(
3
, Pr =
n
-propyl), (MePPh
3
)PbBr
3
(
4
), (EtPPh
3
)PbBr
3
(
5
) and (PrPPh
3
)PbBr
3
(
6
). Their bromoplumbate anions all show 1D chain-like structures formed by PbBr
6
octahedra but with different connection modes. The six hybrid materials possess obvious blue or red shifted band gaps compared with inorganic PbBr
2
due to their different structural features. Their PL emission colors realize rational regulation ranging from bluish green to orange.
Different alkylated benzothiazole and triphenylphosphine cations are used to adjust the optical absorption and photoluminescence properties of inorganic-organic hybrid bromoplumbates.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d3ce00931a</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-6998-9476</orcidid><orcidid>https://orcid.org/0000-0003-1456-9858</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1466-8033 |
| ispartof | CrystEngComm, 2023-12, Vol.25 (47), p.6556-6567 |
| issn | 1466-8033 1466-8033 |
| language | eng |
| recordid | cdi_rsc_primary_d3ce00931a |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Alkylation Crystal structure Optical properties Photoluminescence |
| title | Regulating the crystal and electronic structures and optical properties of hybrid bromoplumbates with alkylated N, S- or P-containing aromatic cations |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-22T09%3A20%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Regulating%20the%20crystal%20and%20electronic%20structures%20and%20optical%20properties%20of%20hybrid%20bromoplumbates%20with%20alkylated%20N,%20S-%20or%20P-containing%20aromatic%20cations&rft.jtitle=CrystEngComm&rft.au=Gao,%20Cheng-Cheng&rft.date=2023-12-04&rft.volume=25&rft.issue=47&rft.spage=6556&rft.epage=6567&rft.pages=6556-6567&rft.issn=1466-8033&rft.eissn=1466-8033&rft_id=info:doi/10.1039/d3ce00931a&rft_dat=%3Cproquest_rsc_p%3E2896682603%3C/proquest_rsc_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c240t-7bcb45f73986aa67986766516f89a18aea91951383f17692b5229cefd28d42173%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2896682603&rft_id=info:pmid/&rfr_iscdi=true |