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Intercalates of BiSe studied by time-resolved powder X-ray diffraction and neutron diffraction
Intercalation of lithium and ammonia into the layered semiconductor Bi 2 Se 3 proceeds via a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical manip...
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| Published in: | Dalton transactions : an international journal of inorganic chemistry 2021-08, Vol.5 (33), p.11376-11379 |
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| Main Authors: | , , , , , |
| Format: | Article |
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| container_end_page | 11379 |
| container_issue | 33 |
| container_start_page | 11376 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 5 |
| creator | Kamminga, Machteld E Cassidy, Simon J Jana, Partha P Elgaml, Mahmoud Kelly, Nicola D Clarke, Simon J |
| description | Intercalation of lithium and ammonia into the layered semiconductor Bi
2
Se
3
proceeds
via
a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical manipulation.
New lithium amide/ammonia intercalates of Bi
2
Se
3
are revealed using
in situ
X-ray powder diffraction. |
| doi_str_mv | 10.1039/d1dt00960e |
| format | article |
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2
Se
3
proceeds
via
a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical manipulation.
New lithium amide/ammonia intercalates of Bi
2
Se
3
are revealed using
in situ
X-ray powder diffraction.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d1dt00960e</identifier><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2021-08, Vol.5 (33), p.11376-11379</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,786,790,27957,27958</link.rule.ids></links><search><creatorcontrib>Kamminga, Machteld E</creatorcontrib><creatorcontrib>Cassidy, Simon J</creatorcontrib><creatorcontrib>Jana, Partha P</creatorcontrib><creatorcontrib>Elgaml, Mahmoud</creatorcontrib><creatorcontrib>Kelly, Nicola D</creatorcontrib><creatorcontrib>Clarke, Simon J</creatorcontrib><title>Intercalates of BiSe studied by time-resolved powder X-ray diffraction and neutron diffraction</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Intercalation of lithium and ammonia into the layered semiconductor Bi
2
Se
3
proceeds
via
a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical manipulation.
New lithium amide/ammonia intercalates of Bi
2
Se
3
are revealed using
in situ
X-ray powder diffraction.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjjsLwjAURoMoWB-Lu3D_QDVJa0tXRdFZBydLbG4h0hc3qdJ_r4Oom9N3OGf5GJsJvhA8SJZaaMd5EnHsMU-EcewnMgj7H5bRkI2svXEuJV9Jj10OlUPKVKEcWqhzWJsjgnWtNqjh2oEzJfqEti7uL9HUD40EZ59UB9rkOanMmboCVWmosHX04h8_YYNcFRan7x2z-W572ux9slnakCkVden3dPCvPwEbpkZZ</recordid><startdate>20210824</startdate><enddate>20210824</enddate><creator>Kamminga, Machteld E</creator><creator>Cassidy, Simon J</creator><creator>Jana, Partha P</creator><creator>Elgaml, Mahmoud</creator><creator>Kelly, Nicola D</creator><creator>Clarke, Simon J</creator><scope/></search><sort><creationdate>20210824</creationdate><title>Intercalates of BiSe studied by time-resolved powder X-ray diffraction and neutron diffraction</title><author>Kamminga, Machteld E ; Cassidy, Simon J ; Jana, Partha P ; Elgaml, Mahmoud ; Kelly, Nicola D ; Clarke, Simon J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d1dt00960e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2021</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Kamminga, Machteld E</creatorcontrib><creatorcontrib>Cassidy, Simon J</creatorcontrib><creatorcontrib>Jana, Partha P</creatorcontrib><creatorcontrib>Elgaml, Mahmoud</creatorcontrib><creatorcontrib>Kelly, Nicola D</creatorcontrib><creatorcontrib>Clarke, Simon J</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kamminga, Machteld E</au><au>Cassidy, Simon J</au><au>Jana, Partha P</au><au>Elgaml, Mahmoud</au><au>Kelly, Nicola D</au><au>Clarke, Simon J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intercalates of BiSe studied by time-resolved powder X-ray diffraction and neutron diffraction</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2021-08-24</date><risdate>2021</risdate><volume>5</volume><issue>33</issue><spage>11376</spage><epage>11379</epage><pages>11376-11379</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><notes>10.1039/d1dt00960e</notes><notes>Electronic supplementary information (ESI) available. See DOI</notes><abstract>Intercalation of lithium and ammonia into the layered semiconductor Bi
2
Se
3
proceeds
via
a hyperextended (by >60%) ammonia-rich intercalate, to eventually produce a layered compound with lithium amide intercalated between the bismuth selenide layers which offers scope for further chemical manipulation.
New lithium amide/ammonia intercalates of Bi
2
Se
3
are revealed using
in situ
X-ray powder diffraction.</abstract><doi>10.1039/d1dt00960e</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2021-08, Vol.5 (33), p.11376-11379 |
| issn | 1477-9226 1477-9234 |
| language | |
| recordid | cdi_rsc_primary_d1dt00960e |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| title | Intercalates of BiSe studied by time-resolved powder X-ray diffraction and neutron diffraction |
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