Loading…
Iron, Cobalt and Nickel Carbide--Carbonyl Clusters by CO Scission
A new approach to the synthesis in good yields of known cobalt and iron carbide--carbonyl clusters by CO cleavage in mild conditions is reported. Cleavage of CO results from attaching an acetyl or benzoyl carbocation to the oxygen atom, and by transfer of electrons from an external source. This synt...
Saved in:
| Published in: | Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences 1982-12, Vol.308 (1501), p.47-57 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3 |
| container_end_page | 57 |
| container_issue | 1501 |
| container_start_page | 47 |
| container_title | Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences |
| container_volume | 308 |
| creator | Longoni, G. Ceriotti, A. Della Pergola, R. Manassero, M. Perego, M. Piro, G. Sansoni, M. |
| description | A new approach to the synthesis in good yields of known cobalt and iron carbide--carbonyl clusters by CO cleavage in mild
conditions is reported. Cleavage of CO results from attaching an acetyl or benzoyl carbocation to the oxygen atom, and by
transfer of electrons from an external source. This synthetic approach to carbide molecular clusters may be of some significance
with respect to the formation of carbide atoms on to metal crystallites. Attempts to synthesize nickel carbide clusters with
the same approach have only been partly successful. The new [Ni$_{9}$C(CO)$_{17}$]$^{2-}$ and [Ni$_{8}$C(CO)$_{16}$]$^{2-}$
have been obtained more conveniently from the reaction of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with CCl$_{4}$. The related reaction
of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with Co$_{3}$(CO)$_{9}$CCl results in the formation of the mixed-metal carbide cluster [Co$_{3}$Ni$_{9}$C(CO)$_{20}$]$^{3-}$.
This compound is degraded under a carbon monoxide and hydrogen mixture (25 degrees C, 1 atm) to Ni(CO)$_{4}$, [Co(CO)$_{4}$]$^{-}$
and ethane. Intermediate formation of [Co$_{3}$Ni$_{7}$(C-C)(CO)$_{15}$]$^{3-}$, in which the two carbide atoms show an interatomic
separation of 1.43 angstrom, or of a related species, would provide a possible pathway for C-C bond formation. |
| doi_str_mv | 10.1098/rsta.1982.0145 |
| format | article |
| fullrecord | <record><control><sourceid>jstor_royal</sourceid><recordid>TN_cdi_royalsociety_journals_10_1098_rsta_1982_0145</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><jstor_id>37219</jstor_id><sourcerecordid>37219</sourcerecordid><originalsourceid>FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3</originalsourceid><addsrcrecordid>eNp9UEtLxDAQDqKgrl49eOoPsLuZpOm2F2EpvkAUfIC3kKSJZq3NknSV-utNd0UU0VNmJvM95kPoAPAYcFlMfOjEGMqCjDFkbAPtQDaFlJQ52Yw1zbOUYfqwjXZDmGMMkDOyg2YX3rVHSeWkaLpEtHVyZdWzbpJKeGlrnaZD4do-Tppl6LQPieyT6jq5VTYE69o9tGVEE_T-5ztC96cnd9V5enl9dlHNLlOVUdalOZiyyIhktJYlk7muJQajMJSSytooAQSACCEVYQU1UmspRUZUSbUkojB0hMZrXuVdCF4bvvD2RfieA-ZDAHwIgA8B8CGACAhrgHd9NOaU1V3P527p29jym9u7GZQ0e6W4sMAwcFxQwIxOI9-7XazohgUeF3i8dan5au2nzG9V-p_qn14P16h56Jz_uoxOSXQwQpP155N9fHqzXvMf3LFZRLLB5cpfNo2I438Rg7hybafb7juOm2XT8EVt6Adc5bXf</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Iron, Cobalt and Nickel Carbide--Carbonyl Clusters by CO Scission</title><source>Royal Society Package S</source><source>JSTOR Archival Journals and Primary Sources Collection【Remote access available】</source><creator>Longoni, G. ; Ceriotti, A. ; Della Pergola, R. ; Manassero, M. ; Perego, M. ; Piro, G. ; Sansoni, M.</creator><creatorcontrib>Longoni, G. ; Ceriotti, A. ; Della Pergola, R. ; Manassero, M. ; Perego, M. ; Piro, G. ; Sansoni, M.</creatorcontrib><description>A new approach to the synthesis in good yields of known cobalt and iron carbide--carbonyl clusters by CO cleavage in mild
conditions is reported. Cleavage of CO results from attaching an acetyl or benzoyl carbocation to the oxygen atom, and by
transfer of electrons from an external source. This synthetic approach to carbide molecular clusters may be of some significance
with respect to the formation of carbide atoms on to metal crystallites. Attempts to synthesize nickel carbide clusters with
the same approach have only been partly successful. The new [Ni$_{9}$C(CO)$_{17}$]$^{2-}$ and [Ni$_{8}$C(CO)$_{16}$]$^{2-}$
have been obtained more conveniently from the reaction of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with CCl$_{4}$. The related reaction
of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with Co$_{3}$(CO)$_{9}$CCl results in the formation of the mixed-metal carbide cluster [Co$_{3}$Ni$_{9}$C(CO)$_{20}$]$^{3-}$.
This compound is degraded under a carbon monoxide and hydrogen mixture (25 degrees C, 1 atm) to Ni(CO)$_{4}$, [Co(CO)$_{4}$]$^{-}$
and ethane. Intermediate formation of [Co$_{3}$Ni$_{7}$(C-C)(CO)$_{15}$]$^{3-}$, in which the two carbide atoms show an interatomic
separation of 1.43 angstrom, or of a related species, would provide a possible pathway for C-C bond formation.</description><identifier>ISSN: 1364-503X</identifier><identifier>ISSN: 0080-4614</identifier><identifier>EISSN: 1471-2962</identifier><identifier>EISSN: 2054-0272</identifier><identifier>DOI: 10.1098/rsta.1982.0145</identifier><language>eng</language><publisher>London: The Royal Society</publisher><subject>Adducts ; Atoms ; Carbides ; Carbon monoxide ; Chlorides ; Cobalt ; Iron ; Molecular clusters ; Oxygen ; Rock cleavage</subject><ispartof>Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences, 1982-12, Vol.308 (1501), p.47-57</ispartof><rights>Copyright 1982 The Royal Society</rights><rights>Scanned images copyright © 2017, Royal Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3</citedby><cites>FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.jstor.org/stable/pdf/37219$$EPDF$$P50$$Gjstor$$H</linktopdf><linktohtml>$$Uhttps://www.jstor.org/stable/37219$$EHTML$$P50$$Gjstor$$H</linktohtml><link.rule.ids>315,786,790,3343,3344,27179,27957,27958,55909,55919,58593,58826</link.rule.ids></links><search><creatorcontrib>Longoni, G.</creatorcontrib><creatorcontrib>Ceriotti, A.</creatorcontrib><creatorcontrib>Della Pergola, R.</creatorcontrib><creatorcontrib>Manassero, M.</creatorcontrib><creatorcontrib>Perego, M.</creatorcontrib><creatorcontrib>Piro, G.</creatorcontrib><creatorcontrib>Sansoni, M.</creatorcontrib><title>Iron, Cobalt and Nickel Carbide--Carbonyl Clusters by CO Scission</title><title>Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences</title><addtitle>Phil. Trans. R. Soc. Lond. A</addtitle><description>A new approach to the synthesis in good yields of known cobalt and iron carbide--carbonyl clusters by CO cleavage in mild
conditions is reported. Cleavage of CO results from attaching an acetyl or benzoyl carbocation to the oxygen atom, and by
transfer of electrons from an external source. This synthetic approach to carbide molecular clusters may be of some significance
with respect to the formation of carbide atoms on to metal crystallites. Attempts to synthesize nickel carbide clusters with
the same approach have only been partly successful. The new [Ni$_{9}$C(CO)$_{17}$]$^{2-}$ and [Ni$_{8}$C(CO)$_{16}$]$^{2-}$
have been obtained more conveniently from the reaction of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with CCl$_{4}$. The related reaction
of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with Co$_{3}$(CO)$_{9}$CCl results in the formation of the mixed-metal carbide cluster [Co$_{3}$Ni$_{9}$C(CO)$_{20}$]$^{3-}$.
This compound is degraded under a carbon monoxide and hydrogen mixture (25 degrees C, 1 atm) to Ni(CO)$_{4}$, [Co(CO)$_{4}$]$^{-}$
and ethane. Intermediate formation of [Co$_{3}$Ni$_{7}$(C-C)(CO)$_{15}$]$^{3-}$, in which the two carbide atoms show an interatomic
separation of 1.43 angstrom, or of a related species, would provide a possible pathway for C-C bond formation.</description><subject>Adducts</subject><subject>Atoms</subject><subject>Carbides</subject><subject>Carbon monoxide</subject><subject>Chlorides</subject><subject>Cobalt</subject><subject>Iron</subject><subject>Molecular clusters</subject><subject>Oxygen</subject><subject>Rock cleavage</subject><issn>1364-503X</issn><issn>0080-4614</issn><issn>1471-2962</issn><issn>2054-0272</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNp9UEtLxDAQDqKgrl49eOoPsLuZpOm2F2EpvkAUfIC3kKSJZq3NknSV-utNd0UU0VNmJvM95kPoAPAYcFlMfOjEGMqCjDFkbAPtQDaFlJQ52Yw1zbOUYfqwjXZDmGMMkDOyg2YX3rVHSeWkaLpEtHVyZdWzbpJKeGlrnaZD4do-Tppl6LQPieyT6jq5VTYE69o9tGVEE_T-5ztC96cnd9V5enl9dlHNLlOVUdalOZiyyIhktJYlk7muJQajMJSSytooAQSACCEVYQU1UmspRUZUSbUkojB0hMZrXuVdCF4bvvD2RfieA-ZDAHwIgA8B8CGACAhrgHd9NOaU1V3P527p29jym9u7GZQ0e6W4sMAwcFxQwIxOI9-7XazohgUeF3i8dan5au2nzG9V-p_qn14P16h56Jz_uoxOSXQwQpP155N9fHqzXvMf3LFZRLLB5cpfNo2I438Rg7hybafb7juOm2XT8EVt6Adc5bXf</recordid><startdate>19821220</startdate><enddate>19821220</enddate><creator>Longoni, G.</creator><creator>Ceriotti, A.</creator><creator>Della Pergola, R.</creator><creator>Manassero, M.</creator><creator>Perego, M.</creator><creator>Piro, G.</creator><creator>Sansoni, M.</creator><general>The Royal Society</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19821220</creationdate><title>Iron, Cobalt and Nickel Carbide--Carbonyl Clusters by CO Scission</title><author>Longoni, G. ; Ceriotti, A. ; Della Pergola, R. ; Manassero, M. ; Perego, M. ; Piro, G. ; Sansoni, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><topic>Adducts</topic><topic>Atoms</topic><topic>Carbides</topic><topic>Carbon monoxide</topic><topic>Chlorides</topic><topic>Cobalt</topic><topic>Iron</topic><topic>Molecular clusters</topic><topic>Oxygen</topic><topic>Rock cleavage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Longoni, G.</creatorcontrib><creatorcontrib>Ceriotti, A.</creatorcontrib><creatorcontrib>Della Pergola, R.</creatorcontrib><creatorcontrib>Manassero, M.</creatorcontrib><creatorcontrib>Perego, M.</creatorcontrib><creatorcontrib>Piro, G.</creatorcontrib><creatorcontrib>Sansoni, M.</creatorcontrib><collection>CrossRef</collection><jtitle>Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Longoni, G.</au><au>Ceriotti, A.</au><au>Della Pergola, R.</au><au>Manassero, M.</au><au>Perego, M.</au><au>Piro, G.</au><au>Sansoni, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Iron, Cobalt and Nickel Carbide--Carbonyl Clusters by CO Scission</atitle><jtitle>Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences</jtitle><stitle>Phil. Trans. R. Soc. Lond. A</stitle><date>1982-12-20</date><risdate>1982</risdate><volume>308</volume><issue>1501</issue><spage>47</spage><epage>57</epage><pages>47-57</pages><issn>1364-503X</issn><issn>0080-4614</issn><eissn>1471-2962</eissn><eissn>2054-0272</eissn><abstract>A new approach to the synthesis in good yields of known cobalt and iron carbide--carbonyl clusters by CO cleavage in mild
conditions is reported. Cleavage of CO results from attaching an acetyl or benzoyl carbocation to the oxygen atom, and by
transfer of electrons from an external source. This synthetic approach to carbide molecular clusters may be of some significance
with respect to the formation of carbide atoms on to metal crystallites. Attempts to synthesize nickel carbide clusters with
the same approach have only been partly successful. The new [Ni$_{9}$C(CO)$_{17}$]$^{2-}$ and [Ni$_{8}$C(CO)$_{16}$]$^{2-}$
have been obtained more conveniently from the reaction of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with CCl$_{4}$. The related reaction
of [Ni$_{6}$(CO)$_{12}$]$^{2-}$ with Co$_{3}$(CO)$_{9}$CCl results in the formation of the mixed-metal carbide cluster [Co$_{3}$Ni$_{9}$C(CO)$_{20}$]$^{3-}$.
This compound is degraded under a carbon monoxide and hydrogen mixture (25 degrees C, 1 atm) to Ni(CO)$_{4}$, [Co(CO)$_{4}$]$^{-}$
and ethane. Intermediate formation of [Co$_{3}$Ni$_{7}$(C-C)(CO)$_{15}$]$^{3-}$, in which the two carbide atoms show an interatomic
separation of 1.43 angstrom, or of a related species, would provide a possible pathway for C-C bond formation.</abstract><cop>London</cop><pub>The Royal Society</pub><doi>10.1098/rsta.1982.0145</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1364-503X |
| ispartof | Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences, 1982-12, Vol.308 (1501), p.47-57 |
| issn | 1364-503X 0080-4614 1471-2962 2054-0272 |
| language | eng |
| recordid | cdi_royalsociety_journals_10_1098_rsta_1982_0145 |
| source | Royal Society Package S; JSTOR Archival Journals and Primary Sources Collection【Remote access available】 |
| subjects | Adducts Atoms Carbides Carbon monoxide Chlorides Cobalt Iron Molecular clusters Oxygen Rock cleavage |
| title | Iron, Cobalt and Nickel Carbide--Carbonyl Clusters by CO Scission |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-23T06%3A28%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-jstor_royal&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Iron,%20Cobalt%20and%20Nickel%20Carbide--Carbonyl%20Clusters%20by%20CO%20Scission&rft.jtitle=Philosophical%20transactions%20of%20the%20Royal%20Society%20of%20London.%20Series%20A:%20Mathematical%20and%20physical%20sciences&rft.au=Longoni,%20G.&rft.date=1982-12-20&rft.volume=308&rft.issue=1501&rft.spage=47&rft.epage=57&rft.pages=47-57&rft.issn=1364-503X&rft.eissn=1471-2962&rft_id=info:doi/10.1098/rsta.1982.0145&rft_dat=%3Cjstor_royal%3E37219%3C/jstor_royal%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c435t-61f9842b53db95b6edb01fc019b3bdfca12112aabc2583fbeebba42c93eb2a8f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rft_jstor_id=37219&rfr_iscdi=true |