Loading…
Dynamic Covalent Self‐Assembly of Chloride‐ and Ion‐Pair‐Templated Cryptates
While supramolecular hosts capable of binding and transporting anions and ion pairs are now widely available, self‐assembled architectures are still rare, even though they offer an inherent mechanism for the release of the guest ion(s). In this work, we report the dynamic covalent self‐assembly of t...
Saved in:
Published in: | Angewandte Chemie International Edition 2022-07, Vol.61 (28), p.e202201831-n/a |
---|---|
Main Authors: | , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
cited_by | cdi_FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3 |
---|---|
cites | cdi_FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3 |
container_end_page | n/a |
container_issue | 28 |
container_start_page | e202201831 |
container_title | Angewandte Chemie International Edition |
container_volume | 61 |
creator | Hollstein, Selina Shyshov, Oleksandr Hanževački, Marko Zhao, Jie Rudolf, Tamara Jäger, Christof M. Delius, Max |
description | While supramolecular hosts capable of binding and transporting anions and ion pairs are now widely available, self‐assembled architectures are still rare, even though they offer an inherent mechanism for the release of the guest ion(s). In this work, we report the dynamic covalent self‐assembly of tripodal, urea‐based anion cryptates that are held together by two orthoester bridgeheads. These hosts exhibit affinity for anions such as Cl−, Br− or I− in the moderate range that is typically advantageous for applications in membrane transport. In unprecedented experiments, we were able to dissociate the Cs⋅Cl ion pair by simultaneously assembling suitably sized orthoester hosts around the Cs+ and the Cl− ion.
The combination of urea‐based diols and simple orthoesters allowed the dynamic covalent encapsulation of the chloride ion and the simultaneous encapsulation of both ions present in cesium chloride. |
doi_str_mv | 10.1002/anie.202201831 |
format | article |
fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9400851</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2647655543</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3</originalsourceid><addsrcrecordid>eNqFkU1v1DAQhi0Eou3ClSOKxIVLFn8mzgVplbawUgVILGfLScbUlRMv9m5RbvwEfiO_hKm2LB8XTjMeP_NqZl5CnjG6ZJTyV3bysOSUc8q0YA_IKVOclaKuxUPMpRBlrRU7IWc53yCvNa0ekxOhhJbYdUo25_NkR98Xbby1AaZd8RGC-_Ht-ypnGLswF9EV7XWIyQ-A5cJOQ7GOE6YfrE8YNjBug93BULRp3u4wy0_II2dDhqf3cUE-XV5s2rfl1fs363Z1Vfay0qx0TIDrHeWNbCROpu0gNG-glszSTneMQSclrxWwwYG2TFtBpR5sr6jr8bEgrw-62303wtDj-MkGs01-tGk20Xrz98_kr83neGsaSSmeBQVe3guk-GUPeWdGn3sIwU4Q99nwStaVUgrvuCAv_kFv4j5NuB5SWjR1raoKqeWB6lPMOYE7DsOouTPM3BlmjoZhw_M_VzjivxxCoDkAX32A-T9yZvVuffFb_Cdi2KY9</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2683977566</pqid></control><display><type>article</type><title>Dynamic Covalent Self‐Assembly of Chloride‐ and Ion‐Pair‐Templated Cryptates</title><source>Wiley</source><creator>Hollstein, Selina ; Shyshov, Oleksandr ; Hanževački, Marko ; Zhao, Jie ; Rudolf, Tamara ; Jäger, Christof M. ; Delius, Max</creator><creatorcontrib>Hollstein, Selina ; Shyshov, Oleksandr ; Hanževački, Marko ; Zhao, Jie ; Rudolf, Tamara ; Jäger, Christof M. ; Delius, Max</creatorcontrib><description>While supramolecular hosts capable of binding and transporting anions and ion pairs are now widely available, self‐assembled architectures are still rare, even though they offer an inherent mechanism for the release of the guest ion(s). In this work, we report the dynamic covalent self‐assembly of tripodal, urea‐based anion cryptates that are held together by two orthoester bridgeheads. These hosts exhibit affinity for anions such as Cl−, Br− or I− in the moderate range that is typically advantageous for applications in membrane transport. In unprecedented experiments, we were able to dissociate the Cs⋅Cl ion pair by simultaneously assembling suitably sized orthoester hosts around the Cs+ and the Cl− ion.
The combination of urea‐based diols and simple orthoesters allowed the dynamic covalent encapsulation of the chloride ion and the simultaneous encapsulation of both ions present in cesium chloride.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>ISSN: 1521-3773</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202201831</identifier><identifier>PMID: 35384202</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Anions ; Assembling ; Assembly ; Chloride Binding ; Host–Guest Chemistry ; Ion Pairs ; Molecular Dynamics ; Self-Assembly ; Urea</subject><ispartof>Angewandte Chemie International Edition, 2022-07, Vol.61 (28), p.e202201831-n/a</ispartof><rights>2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH</rights><rights>2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.</rights><rights>2022. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3</citedby><cites>FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3</cites><orcidid>0000-0002-1802-1892 ; 0000-0002-0464-8782 ; 0000-0003-1852-2969</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202201831$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202201831$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>230,315,786,790,891,27957,27958,50923,51032</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35384202$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hollstein, Selina</creatorcontrib><creatorcontrib>Shyshov, Oleksandr</creatorcontrib><creatorcontrib>Hanževački, Marko</creatorcontrib><creatorcontrib>Zhao, Jie</creatorcontrib><creatorcontrib>Rudolf, Tamara</creatorcontrib><creatorcontrib>Jäger, Christof M.</creatorcontrib><creatorcontrib>Delius, Max</creatorcontrib><title>Dynamic Covalent Self‐Assembly of Chloride‐ and Ion‐Pair‐Templated Cryptates</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>While supramolecular hosts capable of binding and transporting anions and ion pairs are now widely available, self‐assembled architectures are still rare, even though they offer an inherent mechanism for the release of the guest ion(s). In this work, we report the dynamic covalent self‐assembly of tripodal, urea‐based anion cryptates that are held together by two orthoester bridgeheads. These hosts exhibit affinity for anions such as Cl−, Br− or I− in the moderate range that is typically advantageous for applications in membrane transport. In unprecedented experiments, we were able to dissociate the Cs⋅Cl ion pair by simultaneously assembling suitably sized orthoester hosts around the Cs+ and the Cl− ion.
The combination of urea‐based diols and simple orthoesters allowed the dynamic covalent encapsulation of the chloride ion and the simultaneous encapsulation of both ions present in cesium chloride.</description><subject>Anions</subject><subject>Assembling</subject><subject>Assembly</subject><subject>Chloride Binding</subject><subject>Host–Guest Chemistry</subject><subject>Ion Pairs</subject><subject>Molecular Dynamics</subject><subject>Self-Assembly</subject><subject>Urea</subject><issn>1433-7851</issn><issn>1521-3773</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkU1v1DAQhi0Eou3ClSOKxIVLFn8mzgVplbawUgVILGfLScbUlRMv9m5RbvwEfiO_hKm2LB8XTjMeP_NqZl5CnjG6ZJTyV3bysOSUc8q0YA_IKVOclaKuxUPMpRBlrRU7IWc53yCvNa0ekxOhhJbYdUo25_NkR98Xbby1AaZd8RGC-_Ht-ypnGLswF9EV7XWIyQ-A5cJOQ7GOE6YfrE8YNjBug93BULRp3u4wy0_II2dDhqf3cUE-XV5s2rfl1fs363Z1Vfay0qx0TIDrHeWNbCROpu0gNG-glszSTneMQSclrxWwwYG2TFtBpR5sr6jr8bEgrw-62303wtDj-MkGs01-tGk20Xrz98_kr83neGsaSSmeBQVe3guk-GUPeWdGn3sIwU4Q99nwStaVUgrvuCAv_kFv4j5NuB5SWjR1raoKqeWB6lPMOYE7DsOouTPM3BlmjoZhw_M_VzjivxxCoDkAX32A-T9yZvVuffFb_Cdi2KY9</recordid><startdate>20220711</startdate><enddate>20220711</enddate><creator>Hollstein, Selina</creator><creator>Shyshov, Oleksandr</creator><creator>Hanževački, Marko</creator><creator>Zhao, Jie</creator><creator>Rudolf, Tamara</creator><creator>Jäger, Christof M.</creator><creator>Delius, Max</creator><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>24P</scope><scope>WIN</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1802-1892</orcidid><orcidid>https://orcid.org/0000-0002-0464-8782</orcidid><orcidid>https://orcid.org/0000-0003-1852-2969</orcidid></search><sort><creationdate>20220711</creationdate><title>Dynamic Covalent Self‐Assembly of Chloride‐ and Ion‐Pair‐Templated Cryptates</title><author>Hollstein, Selina ; Shyshov, Oleksandr ; Hanževački, Marko ; Zhao, Jie ; Rudolf, Tamara ; Jäger, Christof M. ; Delius, Max</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anions</topic><topic>Assembling</topic><topic>Assembly</topic><topic>Chloride Binding</topic><topic>Host–Guest Chemistry</topic><topic>Ion Pairs</topic><topic>Molecular Dynamics</topic><topic>Self-Assembly</topic><topic>Urea</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hollstein, Selina</creatorcontrib><creatorcontrib>Shyshov, Oleksandr</creatorcontrib><creatorcontrib>Hanževački, Marko</creatorcontrib><creatorcontrib>Zhao, Jie</creatorcontrib><creatorcontrib>Rudolf, Tamara</creatorcontrib><creatorcontrib>Jäger, Christof M.</creatorcontrib><creatorcontrib>Delius, Max</creatorcontrib><collection>Open Access: Wiley-Blackwell Open Access Journals</collection><collection>Wiley Online Library Free Content</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hollstein, Selina</au><au>Shyshov, Oleksandr</au><au>Hanževački, Marko</au><au>Zhao, Jie</au><au>Rudolf, Tamara</au><au>Jäger, Christof M.</au><au>Delius, Max</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dynamic Covalent Self‐Assembly of Chloride‐ and Ion‐Pair‐Templated Cryptates</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2022-07-11</date><risdate>2022</risdate><volume>61</volume><issue>28</issue><spage>e202201831</spage><epage>n/a</epage><pages>e202201831-n/a</pages><issn>1433-7851</issn><issn>1521-3773</issn><eissn>1521-3773</eissn><notes>ObjectType-Article-1</notes><notes>SourceType-Scholarly Journals-1</notes><notes>ObjectType-Feature-2</notes><notes>content type line 23</notes><abstract>While supramolecular hosts capable of binding and transporting anions and ion pairs are now widely available, self‐assembled architectures are still rare, even though they offer an inherent mechanism for the release of the guest ion(s). In this work, we report the dynamic covalent self‐assembly of tripodal, urea‐based anion cryptates that are held together by two orthoester bridgeheads. These hosts exhibit affinity for anions such as Cl−, Br− or I− in the moderate range that is typically advantageous for applications in membrane transport. In unprecedented experiments, we were able to dissociate the Cs⋅Cl ion pair by simultaneously assembling suitably sized orthoester hosts around the Cs+ and the Cl− ion.
The combination of urea‐based diols and simple orthoesters allowed the dynamic covalent encapsulation of the chloride ion and the simultaneous encapsulation of both ions present in cesium chloride.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>35384202</pmid><doi>10.1002/anie.202201831</doi><tpages>8</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-1802-1892</orcidid><orcidid>https://orcid.org/0000-0002-0464-8782</orcidid><orcidid>https://orcid.org/0000-0003-1852-2969</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1433-7851 |
ispartof | Angewandte Chemie International Edition, 2022-07, Vol.61 (28), p.e202201831-n/a |
issn | 1433-7851 1521-3773 1521-3773 |
language | eng |
recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9400851 |
source | Wiley |
subjects | Anions Assembling Assembly Chloride Binding Host–Guest Chemistry Ion Pairs Molecular Dynamics Self-Assembly Urea |
title | Dynamic Covalent Self‐Assembly of Chloride‐ and Ion‐Pair‐Templated Cryptates |
url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-09-21T07%3A25%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dynamic%20Covalent%20Self%E2%80%90Assembly%20of%20Chloride%E2%80%90%20and%20Ion%E2%80%90Pair%E2%80%90Templated%20Cryptates&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Hollstein,%20Selina&rft.date=2022-07-11&rft.volume=61&rft.issue=28&rft.spage=e202201831&rft.epage=n/a&rft.pages=e202201831-n/a&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.202201831&rft_dat=%3Cproquest_pubme%3E2647655543%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4681-f13efcf0294948808ad3829e741a0b8b11eb44275e1dfe8a18a3048dac50fc8a3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2683977566&rft_id=info:pmid/35384202&rfr_iscdi=true |